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Cd2(IO3)(PO4) and Cd1.62Mg0.38(IO3)(PO4): metal iodate-phosphates with large SHG responses and wide band gaps.
Chen, Qian-Qian; Hu, Chun-Li; Yao, Li-Jia; Chen, Jin; Cao, Ming-Yang; Li, Bing-Xuan; Mao, Jiang-Gao.
Afiliação
  • Chen QQ; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
  • Hu CL; University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
  • Yao LJ; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
  • Chen J; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
  • Cao MY; School of Physical Science and Technology, ShanghaiTech University, Shanghai 201210, P. R. China.
  • Li BX; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China.
  • Mao JG; University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
Chem Commun (Camb) ; 58(55): 7694-7697, 2022 Jul 07.
Article em En | MEDLINE | ID: mdl-35730669
ABSTRACT
The first NLO-active metal iodate-phosphates, namely, Cd2(IO3)(PO4) and Cd1.62Mg0.38(IO3)(PO4) (1 and 2), with three types of NLO groups, have been reported. 1 and 2 are isostructural and the structure of 1 features a 3D network formed by the Cd4(IO3)8/4(PO4)6/3 groups. 1 and 2 with strong SHG signals of 4 × and 3.5 × KH2PO4 are promising SHG materials in the visible region.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2022 Tipo de documento: Article