Preparation and SERS performance of silver nanowires arrays on paper by automatic writing method.

Silver nanowire ink was written on the surface of drawing paper by automatic writing method. Scanning electron microscopy was used to characterize the surface morphologies of the drawing paper before and after writing silver nanowires. The effects of fabrication parameters and measurement parameters on silver nanowires arrays were investigated. Crystal violet was selected as the probe molecule to study the SERS performance of silver nanowires arrays. The detection limit of crystal violet was as low as 10-15 mol/L. The uniformity and repeatability of the arrays were also explored, and the relative standard deviation values were about 10%. Moreover, silver nanowires arrays were also relatively stable that SERS signals were still observed after ten weeks. Detection of the crystal violet residue was further achieved on the substrates by continuously pressing nine times. In addition, silver nanowires arrays were also applied to the quantitative analyses of 2, 2'-bipyridyl.