Fluorine on fluorenes.

Dickinson, Cody F; Yang, Justin K; Tius, Marcus A

Dickinson, Cody F; Yang, Justin K; Tius, Marcus A.

Afiliação

Dickinson CF; Chemistry Department, University of Hawaii at Manoa, 2545 The Mall, Honolulu, HI 96822, USA. tius@hawaii.edu.
Yang JK; Chemistry Department, University of Hawaii at Manoa, 2545 The Mall, Honolulu, HI 96822, USA. tius@hawaii.edu.
Tius MA; Chemistry Department, University of Hawaii at Manoa, 2545 The Mall, Honolulu, HI 96822, USA. tius@hawaii.edu.

Org Biomol Chem ; 20(44): 8615-8617, 2022 Nov 16.

Article em En | MEDLINE | ID: mdl-36314529

ABSTRACT

ABSTRACT

A practical synthesis of 1,8-difluorofluorenone and of its (2,7)-dibromo and (2,4,5,7)-tetrabromo derivatives has been developed. Fluorinated fluorenones are the starting materials for polyhalogenated dibenzochrysenes as well as for geodesic hydrocarbons. 2,7-Dibromo-1,8-difluoro-9H-fluoren-9-one was converted to 3,14-dibromo-4,13-difluorodibenzo[g,p]chrysene through a novel strategy.

Assuntos

Fluorenos; Flúor; Fluoretos

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Fluorenos / Flúor Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Estados Unidos

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