Lanthanide-directed metal-organic coordination networks.

ABSTRACT

The synthesis of two-dimensional metal-organic networks (2D-MOCNs) on solid substrates is a rapidly growing field of research due to their potential applications in gas sensing, catalysis, energy storage, spintronics, and quantum information. In addition, the possibility of using lanthanides as coordination nodes makes them a very straightforward alternative to create an ordered array of magnetic atoms on a surface, thus paving the way for their use in information storage at the single-atom level. This feature article reviews the strategies to design two-dimensional periodic nanoarchitectures comprising lanthanide atoms in ultra-high vacuum (UHV) environment, focusing on lanthanide-directed 2D-MOCNs on metal surfaces and decoupling substrates. The characterization of their structure, electronic, and magnetic properties is also discussed, including the use of state-of-the-art scanning probe microscopies and photoelectron spectroscopies, complemented by density functional theory calculations and multiplet simulations.