1.
Chem Commun (Camb)
; 56(76): 11219-11222, 2020 Sep 24.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32818220
RESUMO
By exploiting an established on-surface metallation strategy, we address the ability of the corrolic macrocycle to stabilise transition metal ions in high-valent (III) oxidation states in metal-supported molecular layers. This approach offers a route to engineer adsorbed metal complexes that cannot be easily fabricated by organic synthesis methods and bear a vacant axial coordination site for catalytic conversions.