The dominant role of exciton quenching in PbS quantum-dot-based photovoltaic devices.

We present a quantitative measurement of the number of trapped carriers combined with a measurement of exciton quenching to assess limiting mechanisms for current losses in PbS-quantum-dot-based photovoltaic devices. We use photocurrent intensity dependence and short-wave infrared transient photoluminescence and correlate these with device performance. We find that the effective density of trapped carriers ranges from 1 in 10 to 1 in 10,000 quantum dots, depending on ligand treatment, and that nonradiative exciton quenching, as opposed to recombination with trapped carriers, is likely the limiting mechanism in these devices.

Efficient single photon detection from 500 nm to 5 µm wavelength.

We report on superconducting nanowire single photon detectors (SNSPDs) based on 30 nm wide nanowires with detection efficiency η ∼ 2.6-5.5% in the wavelength range λ = 0.5-5 µm. We compared the sensitivity of 30 nm wide SNSPDs with the sensitivity of SNSPDs based on wider (85 and 50 nm wide) nanowires for λ = 0.5-5 µm. The detection efficiency of the detectors based on the wider nanowires became negligible at shorter wavelengths than the 30 nm wide SNSPDs. Our 30 nm wide SNSPDs showed 2 orders of magnitude higher detection efficiency (η ∼ 2%) up to longer wavelength (λ = 5 µm) than previously reported. On the basis of our simulations, we expect that by changing the optical coupling scheme and by integrating the detectors in an optical cavity, the detection efficiency of our detectors could be increased by a factor of ∼6.

Single photon counting from individual nanocrystals in the infrared.

Experimental restrictions imposed on the collection and detection of shortwave-infrared photons (SWIR) have impeded single molecule work on a large class of materials whose optical activity lies in the SWIR. Here we report the successful observation of room-temperature single nanocrystal photoluminescence at SWIR wavelengths using a highly efficient multielement superconducting nanowire single photon detector. We confirm that the photoluminescence from single lead sulfide nanocrystals is strongly antibunched, demonstrating the feasibility of performing sophisticated photon correlation experiments on individual weak SWIR emitters, and, more broadly, paving the way for sensitive measurements of spectral observables on infrared quantum systems that are incompatible with current detection techniques.

Superconducting nanowire single-photon detectors integrated with optical nano-antennae.

Optical nano-antennae have been integrated with semiconductor lasers to intensify light at the nanoscale and photodiodes to enhance photocurrent. In quantum optics, plasmonic metal structures have been used to enhance nonclassical light emission from single quantum dots. Absorption and detection of single photons from free space could also be enhanced by nanometallic antennae, but this has not previously been demonstrated. Here, we use nano-optical transmission effects in a one-dimensional gold structure, combined with optical cavity resonance, to form optical nano-antennae, which are further used to couple single photons from free space into a 80-nm-wide superconducting nanowire. This antenna-assisted coupling enables a superconducting nanowire single-photon detector with 47% device efficiency at the wavelength of 1550 nm and 9-µm-by-9-µm active area while maintaining a reset time of only 5 ns. We demonstrate nanoscale antenna-like structures to achieve exceptional efficiency and speed in single-photon detection.

High-order temporal coherences of chaotic and laser light.

We demonstrate a new approach to measuring high-order temporal coherences that uses a four-element superconducting nanowire single-photon detector. The four independent, interleaved single-photon-sensitive elements parse a single spatial mode of an optical beam over dimensions smaller than the minimum diffraction-limited spot size. Integrating this device with four-channel time-tagging electronics to generate multi-start, multi-stop histograms enables measurement of temporal coherences up to fourth order for a continuous range of all associated time delays. We observe high-order photon bunching from a chaotic, pseudo-thermal light source, measuring maximum third- and fourth-order coherence values of 5.87 +/- 0.17 and 23.1 +/- 1.8, respectively, in agreement with the theoretically predicted values of 3! = 6 and 4! = 24. Laser light, by contrast, is confirmed to have coherence values of approximately 1 for second, third and fourth orders at all time delays.

Fiber-coupled nanowire photon counter at 1550 nm with 24% system detection efficiency.

We developed a fiber-coupled superconducting nanowire single-photon detector system in a close-cycled cryocooler and achieved 24% and 22% system detection efficiencies at wavelengths of 1550 and 1315 nm, respectively. The maximum dark count rate was approximately 1000 counts/s.

Optical properties of superconducting nanowire single-photon detectors.

We measured the optical absorptance of superconducting nanowire single photon detectors. We found that 200-nm-pitch, 50%-fill-factor devices had an average absorptance of 21% for normally-incident front-illumination of 1.55-microm-wavelength light polarized parallel to the nanowires, and only 10% for perpendicularly-polarized light. We also measured devices with lower fill-factors and narrower wires that were five times more sensitive to parallel-polarized photons than perpendicular-polarized photons. We developed a numerical model that predicts the absorptance of our structures. We also used our measurements, coupled with measurements of device detection efficiencies, to determine the probability of photon detection after an absorption event. We found that, remarkably, absorbed parallel-polarized photons were more likely to result in detection events than perpendicular-polarized photons, and we present a hypothesis that qualitatively explains this result. Finally, we also determined the enhancement of device detection efficiency and absorptance due to the inclusion of an integrated optical cavity over a range of wavelengths (700-1700 nm) on a number of devices, and found good agreement with our numerical model.

Nanowire single-photon detector with an integrated optical cavity and anti-reflection coating.

We have fabricated and tested superconducting single-photon detectors and demonstrated detection efficiencies of 57% at 1550-nm wavelength and 67% at 1064 nm. In addition to the peak detection efficiency, a median detection efficiency of 47.7% was measured over 132 devices at 1550 nm. These measurements were made at 1.8K, with each device biased to 97.5% of its critical current. The high detection efficiencies resulted from the addition of an optical cavity and anti-reflection coating to a nanowire photodetector, creating an integrated nanoelectrophotonic device with enhanced performance relative to the original device. Here, the testing apparatus and the fabrication process are presented. The detection efficiency of devices before and after the addition of optical elements is also reported.

High-performance shortwave-infrared light-emitting devices using core-shell (PbS-CdS) colloidal quantum dots.

Core-shell PbS-CdS quantum dots enhance the peak external quantum efficiency of shortwave-infrared light-emitting devices by up to 50-100-fold (compared with core-only PbS devices). This is more than double the efficiency of previous quantum-dot light-emitting devices operating at wavelengths beyond 1 µm, and results from the passivation of the PbS cores by the CdS shells against in situ photoluminescence quenching.

781 Mbit/s photon-counting optical communications using a superconducting nanowire detector.

We demonstrate 1550 nm photon-counting optical communications with a NbN-nanowire superconducting single-photon detector. Source data are encoded with a rate-1/2 forward-error correcting code and transmitted by use of 32-ary pulse-position modulation at 5 and 10 GHz slot rates. Error-free performance is obtained with -0.5 detected photon per source bit at a source data rate of 781 Mbits/s. To the best of our knowledge, this is the highest reported data rate for a photon-counting receiver.