Total net-rate of 27.88 Tb/s full C-band transmission over 4,550†km using 150†km span length and high-gain EDFA amplification.

We experimentally demonstrate a total net-rate of 27.88 Tb/s for C-band wavelength-division multiplexing (WDM) transmission over an ultralong span-length of 150 km. It is the largest net capacity × span-length product of 4182 Tb/s·km for C-band, single-core, standard single-mode optical fiber transmission over a length of more than 3,000 km. A total of 99 channels, spaced at 50 GHz intervals, are employed for transmitting 32 GBaud probabilistically constellation-shaped (PCS) 64QAM signals with an information entropy of 5.5. High gain amplifiers can achieve wavelength-division multiplexing (WDM) transmission with a bandwidth of 6.25 THz, at a noise figure below 4.3 dB, without the assistance of distributed Raman amplification.

Application of Chitosan/Poly(vinyl alcohol) Stabilized Copper Film Materials for the Borylation of α, ß-Unsaturated Ketones, Morita-Baylis-Hillman Alcohols and Esters in Aqueous Phase.

A chitosan/poly(vinyl alcohol)-stabilized copper nanoparticle (CP@Cu NPs) was used as a heterogeneous catalyst for the borylation of α, ß-unsaturated ketones, MBH alcohols, and MBH esters in mild conditions. This catalyst not only demonstrated remarkable efficiency in synthesizing organoboron compounds but also still maintained excellent reactivity and stability even after seven recycled uses of the catalyst. This methodology provides a gentle and efficient approach to synthesize the organoboron compounds by efficiently constructing carbon-boron bonds.

Cellulose supported TiO2/Cu2O for highly asymmetric conjugate addition of α,ß-unsaturated compounds in aqueous phase.

A series of new kind green cellulose-supported bimetallic TiO2/Cu2O (Cell@TiO2/Cu2O) catalytic materials were obtained by in-situ reduction method employing cellulose as the carrier. The effects of metal percentage composition on the morphology and construction of the catalytic materials were systematically investigated. The Cell@TiO2/Cu2O were characterized by FT-IR, TG, XPS, SEM, TEM, EDS, and the element content was obtained by elemental analysis. Then, the achieved catalytic materials were applied to the chiral borylation reaction of α,ß-unsaturated compounds, including nitrile compounds, esters, and α,ß-unsaturated ketones. Remarkably, this approach provides an efficient strategy to gain an important class of chiral organic boron compounds with target chiral products in high yields as well as enantioselectivities. Besides, the Cell@TiO2/Cu2O could be easily recycled and effectively reused. This work constructed bimetallic TiO2/Cu2O on cellulose as a newly catalyst to obtain chiral boron compounds in aqueous phase.