Recent developments in porous ceramic membranes for wastewater treatment and desalination: A review.

The development of membrane technology has proved vital in providing a sustainable and affordable supply of clean water to address the ever-increasing demand. Though liquid separation applications have been still dominated by polymeric membranes, porous ceramic membranes have gained a commercial foothold in microfiltration (MF) and ultrafiltration (UF) applications due to their hydrophilic nature, lower fouling, ease of cleaning, reliable performance, robust performance with harsh feeds, relative insensitivity to temperature and pH, and stable long-term flux. The enrichment of research and development on porous ceramic membranes extends its focus into advanced membrane separation technologies. The latest emerging nanofiltration (NF) and membrane distillation (MD) applications have witnessed special interests in constructing porous membrane with hydrophilic/functional/hydrophobic properties. However, NF and MD are relatively new, and many shortcomings must be addressed to compete with their polymeric counterparts. For the last three years (2018-2020), state-of-the-art literature on porous ceramic membranes has been collected and critically reviewed. This review highlights the efficiency (permeability, selectivity, and antifouling) of hydrophilic porous ceramic membranes in a wide variety of wastewater treatment applications and hydrophobic porous ceramic membranes in membrane distillation-based desalination applications. A significant focus on pores characteristics, pore sieving phenomenon, nano functionalization, and synergic effect on fouling, the hydrophilic porous ceramic membrane has been discussed. In another part of this review, the role of surface hydrophobicity, water contact angle, liquid entry pressure (LEP), thermal properties, surface micro-roughness, etc., has been discussed for different types of hydrophobic porous ceramic membranes -(a) metal-based, (b) silica-based, (c) other ceramics. Also, this review highlights the potential benefits, drawbacks, and limitations of the porous membrane in applications. Moreover, the prospects are emphasized to overcome the challenges in the field.

Supercritical carbon dioxide extraction of plant phytochemicals for biological and environmental applications - A review.

Recently, supercritical fluid CO2 extraction (SFE) has emerged as a promising and pervasive technology over conventional extraction techniques for various applications, especially for bioactive compounds extraction and environmental pollutants removal. In this context, temperature and pressure regulate the solvent density and thereby effects the yield, selectivity, and biological/therapeutic properties of the extracted components. However, the nature of plant matrices primarily determines the extraction mechanism based on either density or vapor pressure. The present review aims to cover the recent research and developments of SFE technique in the extraction of bioactive plant phytochemicals with high antioxidant, antibacterial, antimalarial, and anti-inflammatory activities, influencing parameters, process conditions, the investigations for improving the yield and selectivity. In another portion of this review focuses on the ecotoxicology and toxic metal recovery applications. Nonpolar properties of Sc-CO2 create strong solvent strength via distinct intermolecular interaction forces with micro-pollutants and toxic metal complexes. This results in efficient removal of these contaminants and makes SFE technology as a superior alternative for conventional solvent-based treatment methods. Moreover, a compelling assessment on the therapeutic, functional, and solvent properties of SFE is rarely focused, and hence this review would add significant value to the SFE based research studies. Furthermore, we mention the limitations and potential of future perspectives related to SFE applications.

Mango leaf extract incorporated chitosan antioxidant film for active food packaging.

Health hazards associated with usage of plastic films for food preservation demands for development of active films from non-toxic and antioxidant rich bio-sources. The reported work highlights the development, characterization and application studies of chitosan films enhanced for their antioxidant activity by mango leaf extract (MLE) incorporation. Effect of MLE variation (1-5%) on the morphology, optical nature, water exposure and mechanical characteristics of the chitosan-MLE composite films was studied. Increase in the MLE concentration resulted in films with increased thickness and decreased moisture content. Contact angle, water solubility and vapor permeability analysis demonstrated the reduced hydrophilicity and water vapor penetrability of the films due to MLE inclusion. MLE films possessed better tensile strength (maximum of 23.06 ±â€¯0.19 MPa) with reduced elongation ratio than the pure chitosan film (18.14 ±â€¯0.72 MPa). Antioxidants assessment in terms of total phenolic content, DPPH radical scavenging, ferric reducing power and ABTS radical scavenging showed improved antioxidant activity with the incremental amounts of MLE in the chitosan films. Microscopic studies revealed the smooth, compact and dense nature of the MLE-chitosan films favouring low oxygen transport rates. Application studies to cashew nuts preservation for 28 days storage indicated 56% higher oxidation resistance for the 5% MLE film than a commercial polyamide/polyethylene film. Results highlight the potential and promising nature of MLE impregnated chitosan films as suitable alternative for active packaging films for food preservation.