XRF calibration with low-cost samples and implementation for quantification of inorganic elements in lipsticks.

In this paper, the preparation of low-cost samples, for the calibration of an energy-dispersive X-ray fluorescence system is presented. The entire procedure is proposed as an undergraduate or postgraduate student laboratory activity, which aims to familiarize students with the procedure of calibration of a spectroscopy-based analytical method through the XRF technique. Furthermore, the use of XRF for the determination of elemental concentrations in samples related to students' interests, was attempted.

Preliminary safety assessment for planning near surface disposal of low-level radioactive waste in Greece.

This paper presents the approach, assumptions, and computational analysis of the preliminary safety assessment, regarding the post-closure period for the disposal of radioactive waste in Greece. The assessment was implemented in the context of the National Program for the disposal of radioactive waste in the country, which is currently in the early stage for the investigation of facility siting. The basis scenario selected for this investigation was the leaching of radionuclides and the exposure in a residence offsite. Moreover, a scenario involving the intrusion in the facility and construction of a dwelling that disturbs the disposal zone is also considered. Due to the significant uncertainties in the current phase, the simulations related to leaching of the waste both in the offsite and intrusion scenarios are based on an uncertainty analysis with 25 site and scenario related parameters. The most important contribution is attributed to Ra-226 with an annual dose equal to about 2 and 3 µSv per MBq disposed, for the offsite and intrusion scenario, respectively. Th-232, Cl-36, C-14, Ag-108m and Pu-239 follow with a dose one order of magnitude less, compared to Ra-226. In the leaching scenarios examined, and for the most dose relevant radionuclides, the exposure related to drinking water from the well and the use of this water to irrigate fruits and vegetables are by far the dominant pathways due to the environmental transfer of the radionuclides and their associated dose coefficients. Th-232 dominates the direct exposure pathways (direct external radiation and plant contamination from the contaminated surface soil) in the intrusion scenario with an annual dose of about 1.4 mSv per Bq/g disposed. Ra-226, Cl-36 and Ag-108m cause exposure levels higher than 0.2 mSv/y per Bq/g disposed in the facility. A wide range was considered for the uncertainty parameters that led to a significant variation in the predicted doses that is expected to envelope the potential exposure for each radionuclide.

A dataset of 112 ligands for the preconcentration of mercury, uranium, lanthanum and other pollutants and heavy metals in water.

This dataset manuscript describes the preparation procedure and lists the preconcentration efficiency of 112 ligands, immobilized on solid-state polymer membranes, for pollutants/elements monitoring in tap water and in environmentally relevant water matrices. Specifically, the energy dispersive X-ray fluorescence (EDXRF) spectra are presented, along with the preconcentration efficiency of each ligand in tap water. The main materials required for membrane preparation include the membrane matrix, a plasticizer, an ionophore, a catalyst (used only when producing anion-selective membranes), and a complexing agent, i.e. ligand. These are simply mixed, applied on a desired surface, here on a BoPET (biaxially-oriented polyethylene terephthalate) film (Mylar®), and left to dry and solidify, producing anion- or cation-selective membranes. Once the membranes are produced, they can be used even by non-specialised personnel directly on the field, which could be of particular importance for low and middle income countries (LMIC) and for remote or insular areas. The membranes can be functionalised with different ligands, suggesting that they can be used for identifying a vast array of different pollutants/elements in water matrices. Here a dataset of 112 ligands, immobilized on anion-selective membranes, are presented in terms of calcium (Ca), iron (Fe), nickel (Ni), zinc (Zn), antimony (Sb), lanthanum (La), uranium (U), copper (Cu), and gold (Au) preconcentration in tap water. Strontium (Sr) was also attempted to be measured, however, quantifiable results were not obtained. Furthermore, data for mercury (Hg) preconcentration, in cation-selective membranes, are also given. The enclosed data show that the most promising ligand for Hg, Ca, Fe, Ni, Zn, Sr, La, U, Cu, and Au preconcentration were 4-(2-Pyridylazo)resorcinol, Eriochrome Black T, di-Ammonium hydrogen citrate, 1,5-Diphenylcarbazide, dithizone, 1,1'-Carbonyldiimidazole, Bis(cyclopentadienyl)titanium dichloride, sodium dibenzyldithiocarbamate, calconcarbonsaure, and dibenzoylmethane, respectively. Interpretation of the data can be found in our previous work [1]. Overall, the main intention of this dataset manuscript is to communicate and promote the adoption of the proposed method by researchers and the water industry alike. This could further advance the method and encourage the assessment of additional ligands or/and pollutants/elements, including heavy metals which are typically found in water.

Trace element analysis of Cretan wines and wine products.

The object of this research is to investigate the ways and the degree of contamination of Cretan grapes from the area of Chania and their alcoholic products, with the elements aluminium, arsenic, cadmium, copper, chromium, iron, lead, manganese, nickel and zinc. Fifteen samples of grapes were collected and used for the production of experimental wines from rinsed and unrinsed grapes. A microwave furnace was used for the digestion and dissolution of the experimental wines, the precipitates that originated in these wines, as well as the wines of the corresponding producers. The analyses of all mentioned samples as well as 34 local alcoholic distillates were performed using total reflection X-ray fluorescence and graphite furnace atomic absorption spectrometry. The concentrations for all the elements that were determined were almost in all cases, well below the maximum permissible levels by the Greek and the European Union legislation.