Recent developments and prospects of sustainable remediation treatments for major contaminants in soil: A review.

Rapid industrialisation and urbanisation are contributing to the entry of emerging contaminants into the environment, posing a significant threat to soil health and quality. Therefore, several remediation technologies have been investigated and tested at a field scale to address the issue. However, these remediation technologies face challenges related to cost-effectiveness, environmental concerns, secondary pollution due to the generation of by-products, long-term pollution leaching risks, and social acceptance. Overcoming these constraints necessitates the implementation of sustainable remediation methodologies that prioritise approaches with minimal environmental ramifications and the most substantial net social and economic advantages. Hence, this review delves into diverse contaminants that threaten soil health and quality. Moreover, it outlines the research imperatives for advancing innovative remediation techniques and effective management strategies to tackle this concern. The review discusses a remediation treatment train approach that encourages resource recovery, strengthens the circular economy, and employs a Life Cycle Assessment (LCA) framework to assess the environmental impacts of different remediation strategies. Additionally, the study explores mechanisms to integrate sustainability principles into soil remediation practices. It underscores the necessity for a comprehensive and systematic approach that takes into account the economic, social, and environmental consequences of remediation methodologies in the development of sustainable solutions.

Experimental investigations and numerical modelling of in-situ reactive caps for PAH contaminated marine sediments.

The present study compared numerical modelling and experimental investigations to evaluate the effectiveness of in-situ reactive capping for marine sediments contaminated by polycyclic aromatic hydrocarbons (PAHs). As a case study, sediment samples from Mar Piccolo (Italy) were analyzed and experiments were undertaken using batch columns. Two types of capping amendments were tested: AquaGate® + 5 % of powdered activated carbon (AG PAC) and Organoclay Reactive Core Mat (OC RCM). The column tests were carried out for 20 days, obtaining a short-term PAH distribution for three cases analysed, which compared the application of the two caps with no intervention. In parallel, in order to evaluate the intervention long term efficacy, an ad-hoc multilayered model predicting PAH concentrations into the sediments and the overlying water column was developed and validated with the experimental results. Both capping systems considerably reduced PAH concentrations in the overlying water, with the highest performance seen in AG PAC for benzo[a]pyrene (99 %) and anthracene (72 %); results also confirmed in the model predictions. In addition, the numerical simulations indicated a good efficiency of both caps over time, obtaining PAH values below the threshold limit in the long term. Although further experiments need to be developed accounting for multiple contamination competitiveness.