Nanocellulose/scleroglucan-enhanced robust, heat-resistant composite hydrogels for oilfield water plugging.

In an oil exploitation process, hydrogel plugging agents can effectively reduce the water-oil intermixing, decrease water extraction volume, and enhance oil recovery rate. The practical applications of traditional polyacrylamide (PAM) hydrogel plugging agents in oilfield are limited by their non-biodegradability, poor mechanical performance, and inferior temperature-resistance. This work developed a mechanically stable and high-temperature-resistant composite hydrogel (STP) by incorporating biodegradable scleroglucan (Slg) and TEMPO-oxidized cellulose nanofibers (TOCN) in the PAM hydrogel. The addition of Slg conferred heat resistance to the PAM hydrogel, while TOCN reinforced the mechanical strength. Anti-aging analyses revealed that the STP endured for 108 h in a saline environment at 140 °C. In the water flooding characterization, the STP displayed a breakthrough pressure of 42.10 psi/ft. at a flow rate of 0.75 cm3/min. Under these extreme conditions, the plugging pressure reached 14.74 psi/ft., meeting the essential criteria for oilfield water plugging. This research demonstrates the potential of polysaccharides in the preparation of sustainable, tough, and heat-resistant water plugging materials.

Modulation of composite hydrogel consisting of TEMPO-oxidized cellulose nanofibers and cationic guar gum.

The applications of hydrogels are prominently affected by the modulation of their structure and performance. We herein systematically implemented the modulation of an all-polysaccharide hydrogel consisting of TEMPO-oxidized cellulose nanofibers (TOCN) and cationic guar gum (CGG). Four different factors including the carboxylate content and size of TOCN, the freezing-thawing treatment and solid content of hydrogel were studied to disclose their influence on the structure and property of TOCN/CGG hydrogel. The results indicated that the increase of carboxylate content of TOCN, the number of freezing-thawing cycles and solid content all increased the crosslinking density of hydrogel as a result of the improved interactions. Accordingly, the hydrogels exhibited more compact structures and enhanced rheological properties. The influence of TOCN size on the hydrogel structure and property was demonstrated to be dependent on the compromise between the exposed functional groups of TOCN and their ability in generating entanglements inside the hydrogel. This work helps shed light on the modulation of hydrogel structure and performance, which might facilitate the exploration of hydrogel applications.