Applications of mathematical modelling for assessing microplastic transport and fate in water environments: a comparative review.

Microplastics in the environment are considered complex pollutants as they are chemical and corrosive-resistant, non-biodegradable and ubiquitous. These microplastics may act as vectors for the dissemination of other pollutants and the transmission of microorganisms into the water environment. The currently available literature reviews focus on analysing the occurrence, environmental effects and methods of microplastic detection, however lacking a wide-scale systematic review and classification of the mathematical microplastic modelling applications. Thus, the current review provides a global overview of the modelling methodologies used for microplastic transport and fate in water environments. This review consolidates, classifies and analyses the methods, model inputs and results of 61 microplastic modelling studies in the last decade (2012-2022). It thoroughly discusses their strengths, weaknesses and common gaps in their modelling framework. Five main modelling types were classified as follows: hydrodynamic, process-based, statistical, mass-balance and machine learning models. Further, categorisations based on the water environments, location and published year of these applications were also adopted. It is concluded that addressed modelling types resulted in relatively reliable outcomes, yet each modelling framework has its strengths and weaknesses. However, common issues were found such as inputs being unrealistically assumed, especially biological processes, and the lack of sufficient field data for model calibration and validation. For future research, it is recommended to incorporate macroplastics' degradation rates, particles of different shapes and sizes and vertical mixing due to biofouling and turbulent conditions and also more experimental data to obtain precise model inputs and standardised sampling methods for surface and column waters.

Variability of leachate quality and polluting potentials in light of leachate pollution index (LPI) - A global perspective.

From a holistic perspective, this review is the first to comprehensively assess and characterise leachate quality from waste disposal facilities (WDFs), landfills and dumpsites, located in 61 countries worldwide. A continent wise grouping approach was adopted to identify the variability of leachate quality and polluting abilities in light of leachate pollution index (LPI). The literature data on leachate quality included 428 samples, with eighteen leachate parameters, classified under, organic, inorganic, and heavy metals. Statistically significant differences in LPI were found between different continents and WDFs demographic data, i.e., type, status, age, rainfall, etc. A negative correlation was found between pH and the majority of studied parameters, especially for heavy metals such as Pb, Zn, As, Hg, Cy, as the decrease in pH intensifies heavy metals' solubility. Based on the studied worldwide leachate data and WDFs age, an LPI rating was identified, where high, intermediate, and low contaminated leachate are typically classified with having an average of 26.5, 23.6 and 17.5, respectively. The provided database in this review could be of great importance in establishing a more comprehensive global databank by including other countries- and site-specific factors that are vital in enhancing the accuracy of LPI and formatting a more representative leachate diagnosis index.