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1.
Small ; 20(12): e2306915, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-37939317

RESUMO

Multi-component composite materials with a magnetic-dielectric synergistic effect exhibit satisfactory electromagnetic wave absorption performance. However, the effective construction of the structure for these multi-component materials to fully exploit the advantages of each component remains a challenge. Inspired by natural biomass, this study utilizes wood as the raw material and successfully prepares high-performance MoS2@Gd2O3/Mxene loaded porous carbon aerogel (MGMCA) composite material through a one-pot hydrothermal method and carbonization treatment process. With a delicate structural design, the MGMCA is endowed with abundant heterogeneous interface structures, favorable impedance matching characteristics, and a magnetic-dielectric synergistic system, thus demonstrating multiple electromagnetic wave loss mechanisms. Benefiting from these advantages, the obtained MGMCA exhibits outstanding electromagnetic wave absorption performance, with a minimum reflection loss of -57.5 dB at an ultra-thin thickness of only 1.9 mm. This research proposes a reliable strategy for the design of multi-component composite materials, providing valuable insight for the design of biomass-based materials as electromagnetic wave absorbers.

2.
Biomacromolecules ; 23(3): 766-778, 2022 03 14.
Artigo em Inglês | MEDLINE | ID: mdl-35049296

RESUMO

Preparation of natural polymer-based highly conductive hydrogels with tunable mechanical properties for applications in flexible electronics is still challenging. Herein, we report a facile method to prepare lignin-based Fe3+-rich, high-conductivity hydrogels via the following two-step process: (1) lignin hydrogels are prepared by cross-linking sulfonated lignin with poly(ethylene glycol) diglycidyl ether (PEGDGE) and (2) Fe3+ ions are impregnated into the lignin hydrogel by simply soaking in FeCl3. Benefiting from Fe3+ ion complexation with catechol groups and other functional groups in lignin, the resultant hydrogels exhibit unique properties, such as high conductivity (as high as 6.69 S·m-1) and excellent mechanical and hydrophobic properties. As a strain sensor, the as-prepared lignin hydrogel shows high sensitivity when detecting various human motions. With the flow of moist air, the Fe3+-rich lignin hydrogel generates an output voltage of 162.8 mV. The assembled supercapacitor of the hydrogel electrolyte demonstrates a high specific capacitance of 301.8 F·g-1, with a maximum energy density of 26.73 Wh·kg-1, a power density of 2.38 kW·kg-1, and a capacitance retention of 94.1% after 10 000 consecutive charge-discharge cycles. These results support the conclusion that lignin-based Fe3+-rich, high-conductivity hydrogels have promising applications in different fields, including sensors and supercapacitors, rendering a new platform for the value-added utilization of lignin.


Assuntos
Hidrogéis , Lignina , Capacitância Elétrica , Condutividade Elétrica , Humanos , Hidrogéis/química , Íons , Lignina/química , Polímeros/química
3.
Biomacromolecules ; 23(6): 2272-2279, 2022 06 13.
Artigo em Inglês | MEDLINE | ID: mdl-35486379

RESUMO

Smart functional fillers can significantly enhance the comprehensive properties of ionic hydrogels, such as their mechanical properties, which are key features of hydrogels in wearable sensor applications. As a plant-derived natural polymer, hemicellulose can serve as smart functional fillers. In this study, tannic acid-modified hemicellulose nanoparticles (TA@HC) and Fe3+ were used in the preparation of PAA/TA@HC/Fe3+ hydrogels. The addition of TA@HC and Fe3+ in the sodium persulfate (SPS) and acrylic acid (AA) polymerization system resulted in a fast gelation process that was completed within a short time (as short as 30 s) at room temperature. The catechol-rich TA and Fe3+ system allows for quick activation of SPS to produce free radicals, generating abundant hydroxyl groups in a short period of time, which was responsible for the fast gelation. Furthermore, due to the TA@HC effect and the dynamic catechol (TA)-Fe3+ redox system, the PAA/TA@HC/Fe3+ hydrogel exhibited excellent mechanical properties with an exceptionally high strain (as high as 5600%), adhesiveness, rapid and efficient self-healing ability, and reproducible self-adhesion onto various substrates. More importantly, asymmetric adhesive PAA/TA@HC/Fe3+ hydrogels were prepared by selective Fe3+ coating of the upper hydrogel surface to render the top surface nonadhesive so that the same hydrogel with different adhesiveness between the upper and bottom surfaces was obtained. The asymmetric adhesive hydrogel design permits the adhesive side to fit comfortably to the skin and the nonadhesive side showing anti-interference against various different pollutant materials, accurately serving as a pressure sensor.


Assuntos
Hidrogéis , Nanopartículas , Adesivos/química , Catecóis , Hidrogéis/química , Íons/química , Polissacarídeos
4.
Environ Res ; 205: 112454, 2022 04 01.
Artigo em Inglês | MEDLINE | ID: mdl-34856163

RESUMO

It's of practical importance but highly challenging for cell immobilization supports to maintain mechanical strength and reduce microbial leakage in environmental and industrial applications. Herein, we developed an agar/κ-carrageenan composite hydrogel to entrap Klebsiella pneumoniae with the combination of nano-Fe3O4 for processing phenol wastes. The agar/carrageenan-K. pneumoniae composite bead showed good pelletizing properties, superior material strength and high cell loading. Introduction of nano-Fe3O4 to the composite gel further enhanced phenol degradation rate by >10% owing to strengthened phenol oxidation by Fe3O4-induced hydroxyl radicals (·OH) and improved mass and electron transfers. 50 successive cycles of degradation and recycling using the agar/carrageenan-K. pneumoniae composite bead showed that 1500 mg/L phenol was fully degraded for all cycles with the highest rate of 55.12 mg L-1·h-1 obtained at the 15th cycles. The improved stability and recyclability render the as-prepared immobilized phenol-degrading bacteria with great potential for industrial applications.


Assuntos
Klebsiella pneumoniae , Fenol , Ágar , Carragenina , Klebsiella pneumoniae/metabolismo , Fenol/metabolismo , Fenóis
5.
Cellulose (Lond) ; 28(13): 8641-8651, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-34305338

RESUMO

Lateral flow assay (LFA) is an important point-of-care (POC) test platform due to the associated portability, on-site testing, and low cost for diagnosis of pathogen infections and disease biomarkers. However, compared to high-end analyzers in hospitals, LFA devices, in particular, paper- based LFA tests, fall short in accuracy. This study focuses on two ways to improve LFAs: (1) using cellulose fibers, rather than glass fibers for a sample pad, and (2) incorporating a one-step simple, facile, and low cost PVA dam into the LFA. Both strategies (cellulose fiber as a sample pad and water dissolvable PVA dam) contributed to delaying the controlled biomolecule's flow through the nitrocellulose membrane's capillary channels resulting in increased bio-recognition time, thus contributing to the enhancement of LFA sensitivity. PVA modified cellulose fiber-based LFA demonstrated 10 times higher sensitivity than the cellulose fiber-based unmodified LFA, whereas 2 times enhancement was obtained in the cellulose fiber-based sample pad LFA compared to the glass fiber-based sample pad LFA. Ultimately, 20 times increase in sensitivity was achieved in the modified LFA device. This study shows that PVA and eco-friendly cellulose fibers could be incorporated into other paper based POC testing devices for future development. SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s10570-021-04083-3.

6.
Angew Chem Int Ed Engl ; 60(2): 889-895, 2021 01 11.
Artigo em Inglês | MEDLINE | ID: mdl-32935922

RESUMO

Functionalized polypeptides have attracted tremendous interest in recent years and found many stimulating applications owing to their tunable physicochemical characteristics including hydrophilicity and stimuli-responsive behavior. The development of new strategies to produce these polymers without metallic contaminants is crucial for their applications in high-value and sensitive domains, such as biomedical, microelectronic, food-packaging, and personal beauty care fields. Herein, a highly efficient strategy to access well-defined site-specific functionalized polypeptides is developed by combining Michael reaction with hydrogen-bonding organocatalytic ROP of NCA. A library of chain-end and chain-middle functionalized polypeptides (14 examples) with predesigned molecular weights and low polydispersities are readily prepared with this approach. Specifically, the whole synthetic process is metal-free, fulfilling high activity and selectivity at room temperature.

7.
Small ; 16(13): e1906567, 2020 04.
Artigo em Inglês | MEDLINE | ID: mdl-32049432

RESUMO

Sensors are of increasing interest since they can be applied to daily life in different areas from various industrial sectors. As a natural nanomaterial, nanocellulose plays a vital role in the development of novel sensors, particularly in the context of constructing multidimensional architectures. This review summarizes the utilization of nanocellulose including cellulose nanofibers, cellulose nanocrystals, and bacterial cellulose for sensor design, mainly focusing on the influence of nanocellulose on the sensing performance of these sensors. Special attention is paid to nanocellulose in different forms (1D, 2D, and 3D) to highlight the impact of nanocellulose constructed structures. The aim is to provide a critical review on the most recent progress (especially after 2017) related to nanocellulose-containing sensors, since there are significantly increasing research activities in this area. Moreover, the outlook for the development of nanocellulose-containing sensors is also provided at the end of this work.


Assuntos
Técnicas Biossensoriais , Celulose , Técnicas de Química Analítica , Nanofibras , Celulose/química , Técnicas de Química Analítica/instrumentação , Nanofibras/química , Nanoestruturas/química
8.
J Sci Food Agric ; 98(8): 3089-3097, 2018 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-29210456

RESUMO

BACKGROUND: Collagen-based films including casings with a promising application in meat industry are still needed to improve its inferior performance. In the present study, the reinforcement of carboxylated cellulose nanofibers (CNF) for collagen film, based on inter-/intra- molecular electrostatic interaction between cationic acid-swollen collagen fiber and anionic carboxylated CNF, was investigated. RESULTS: Adding CNF decreased the zeta-potential but increased particle size of collagen fiber suspension, with little effect on pH. Furthermore, CNF addition led to a higher tensile strength but a lower elongation, and the water vapor and oxygen barrier properties were improved remarkably. Because the CNF content was 50 g kg-1 or lower, the films had a homogeneous interwoven network, and CNF homogeneously embedded into collagen fiber matrix according to the scanning electron microscopy and atomic force microscopy analysis. Additionally, CNF addition increased film thickness and opacity, as well as swelling rate. CONCLUSION: The incorporation of CNF endows collagen fiber films good mechanical and barrier properties over a proper concentration range (≤ 50 g kg-1 collagen fiber), which is closely associated with electrostatic reaction of collagen fiber and CNF and, subsequently, the form of the homogenous, compatible spatial network, indicating a potential applications of CNF in collagenous protein films, such as edible casings. © 2017 Society of Chemical Industry.


Assuntos
Celulose/química , Colágeno/química , Nanofibras/química , Animais , Bovinos , Tecnologia de Alimentos , Microscopia Eletrônica de Varredura , Permeabilidade , Eletricidade Estática , Resistência à Tração
9.
Adv Mater ; : e2406671, 2024 Jul 10.
Artigo em Inglês | MEDLINE | ID: mdl-38988151

RESUMO

Supramolecular hydrogels are typically assembled through weak non-covalent interactions, posing a significant challenge in achieving ultra strength. Developing a higher strength based on molecular/nanoscale engineering concepts is a potential improvement strategy. Herein, a super-tough supramolecular hydrogel is assembled by gradually diffusing lignosulfonate sodium (LS) into a polyvinyl alcohol (PVA) solution. Both simulations and analytical results indicate that the assembly and subsequent enhancement of the crosslinked network are primarily attributed to LS-induced formation and gradual densification of strong crystalline domains within the hydrogel. The optimized hydrogel exhibits impressive mechanical properties with tensile strength of ≈20 MPa, Young's modulus of ≈14 MPa, and toughness of ≈50 MJ m⁻3, making it the strongest lignin-PVA/polymer hydrogel known so far. Moreover, LS provides the supramolecular hydrogel with excellent low-temperature stability (<-60 °C), antibacterial, and UV-blocking capability (≈100%). Interestingly, the diffusion ability of LS is demonstrated for self-restructuring damaged supramolecular hydrogel, achieving 3D patterning on hydrogel surfaces, and enhancing the local strength of the freeze-thaw PVA hydrogel. The goal is to foster a versatile hydrogel platform by combining eco-friendly LS with biocompatible PVA, paving the way for innovation and interdisciplinarity in biomedicine, engineering materials, and forestry science.

10.
Polymers (Basel) ; 16(8)2024 Apr 16.
Artigo em Inglês | MEDLINE | ID: mdl-38675034

RESUMO

Tetracycline (TC) is a common antibiotic; when untreated TC enters the environment, it will cause a negative impact on the human body through the food chain. In the present study, MnO2/MCM-41@Fe3O4 (FeMnMCM) prepared using a hydrothermal and redox method and Camellia oleifera shell-activated carbon (COFAC) prepared through alkali activation were encapsulated using alginate (ALG) and calcium chloride as a cross-linking matrix to give the composite beads COFAC-FeMnMCM-ALG. The resultant COFAC-FeMnMCM-ALG composite beads were then carefully characterized, showing a high immobilization of MnO2/MCM-41@Fe3O4, with porous COFAC as an effective bioadsorbent for enriching the pollutants in the treated samples. These bead catalysts were subsequently applied to the oxidative degradation of TC in a Fenton oxidation system. Several parameters affecting the degradation were investigated, including the H2O2 concentration, catalyst dosage, initial TC concentration, and temperature. A very high catalytic activity towards the degradation of TC was demonstrated. The electron paramagnetic resonance (EPR) and quenching results showed that ·OH and ·O2- were generated in the system, with ·OH as the main radical species. In addition, the COFAC-FeMnMCM-ALG catalyst exhibited excellent recyclability/reusability. We conclude that the as-prepared COFAC-FeMnMCM-ALG composite beads, which integrate MnO2 and Fe3O4 with bioadsorbents, provide a new idea for the design of catalysts for advanced oxidation processes (AOPs) and have great potential in the Fenton oxidation system to degrade toxic pollutants.

11.
Int J Biol Macromol ; 264(Pt 1): 130566, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38432269

RESUMO

Polypeptides, especially star polypeptides, as a unique kind of biological macromolecules have broad applications in biomedical fields such as drug release, gene delivery, tissue engineering, and regenerative medicines due to their close structural similarity to naturally occurring peptides and proteins, biocompatibility, and amino acid functionality. However, the synthesis of star polypeptide mainly relies on the conventional primary amine-initiated ring-opening polymerization (ROP) of N-carboxyanhydrides (NCA) and suffers from low polymerization activity and limited controllability. This study proposes a fast, efficient and metal-free strategy to access star (co)polypeptides by combining the Michael reaction between acrylates and secondary aminoalcohols with the hydrogen-bonding organocatalytic ROP of NCA. This approach enables the preparation of a library of star (co)polypeptides with predesigned molecular weights, narrow molecular weight distributions, tunable arm number, and arm compositions. Importantly, this method exhibits high activity and selectivity at room temperature, making it both practical and versatile in synthesis applications.


Assuntos
Aminoácidos , Peptídeos , Peptídeos/química , Aminoácidos/química , Aminas/química , Polimerização , Metais
12.
Carbohydr Polym ; 341: 122320, 2024 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-38876713

RESUMO

In an oil exploitation process, hydrogel plugging agents can effectively reduce the water-oil intermixing, decrease water extraction volume, and enhance oil recovery rate. The practical applications of traditional polyacrylamide (PAM) hydrogel plugging agents in oilfield are limited by their non-biodegradability, poor mechanical performance, and inferior temperature-resistance. This work developed a mechanically stable and high-temperature-resistant composite hydrogel (STP) by incorporating biodegradable scleroglucan (Slg) and TEMPO-oxidized cellulose nanofibers (TOCN) in the PAM hydrogel. The addition of Slg conferred heat resistance to the PAM hydrogel, while TOCN reinforced the mechanical strength. Anti-aging analyses revealed that the STP endured for 108 h in a saline environment at 140 °C. In the water flooding characterization, the STP displayed a breakthrough pressure of 42.10 psi/ft. at a flow rate of 0.75 cm3/min. Under these extreme conditions, the plugging pressure reached 14.74 psi/ft., meeting the essential criteria for oilfield water plugging. This research demonstrates the potential of polysaccharides in the preparation of sustainable, tough, and heat-resistant water plugging materials.

13.
Int J Biol Macromol ; 274(Pt 2): 133317, 2024 Jun 24.
Artigo em Inglês | MEDLINE | ID: mdl-38925199

RESUMO

Photocatalytic membranes integrate membrane separation and photocatalysis to deliver an efficient solution for water purification, while the top priority is to exploit simple, efficient, renewable, and low-cost photocatalytic membrane materials. We herein propose a facile one-stone-two-birds strategy to construct a multifunctional regenerated cellulose composite membrane decorated by Prussian blue analogue (ZnPBA) microspheres for wastewater purification. The hypotheses are that: 1) ZnCl2 not only serves as a cellulose solvent for tuning cellulose dissolution and regeneration, but also functions as a precursor for in-situ growth of spherical-like ZnPBA; 2) More homogeneous reactions including coordination and hydrogen bonding among Zn2+, [Fe(CN)6]3- and cellulose chains contribute to a rapid and uniform anchoring of ZnPBA microspheres on the regenerated cellulose fibrils (RCFs). Consequently, the resultant ZnPBA/RCM features a high loading of ZnPBA (65.3 wt%) and exhibits excellent treatment efficiency and reusability in terms of photocatalytic degradation of tetracycline (TC) (90.3 % removal efficiency and 54.3 % of mineralization), oil-water separation efficiency (>97.8 % for varying oils) and antibacterial performance (99.4 % for E. coli and 99.2 % for S. aureus). This work paves a simple and useful way for exploiting cellulose-based functional materials for efficient wastewater purification.

14.
Int J Biol Macromol ; 267(Pt 2): 131364, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38583844

RESUMO

3D printing technology demonstrates significant potential for the rapid fabrication of tailored geometric structures. Nevertheless, the prevalent use of fossil-derived compositions in printable inks within the realm of 3D printing results in considerable environmental pollution and ecological consequences. Lignin, the second most abundant biomass source on earth, possesses attributes such as cost-effectiveness, renewability, biodegradability, and non-toxicity. Enriched with active functional groups including hydroxyl, carbonyl, carboxyl, and methyl, coupled with its rigid aromatic ring structure and inherent anti-oxidative and thermoplastic properties, lignin emerges as a promising candidate for formulating printable inks. This comprehensive review presents the utilization of lignin, either in conjunction with functional materials or through the modification of lignin derivatives, as the primary constituent (≥50 wt%) for formulating printable inks across photo-curing-based (SLA/DLP) and extrusion-based (DIW/FDM) printing technologies. Furthermore, lignin as an additive with multi-faceted roles/functions in 3D printing inks is explored. The effects of lignin on the properties of printing inks and printed objects are evaluated. Finally, this review outlines future perspectives, emphasizing key obstacles and potential opportunities for facilitating the high-value utilization of lignin in the realm of 3D printing.


Assuntos
Tinta , Lignina , Impressão Tridimensional , Lignina/química
15.
Carbohydr Polym ; 335: 122069, 2024 Jul 01.
Artigo em Inglês | MEDLINE | ID: mdl-38616091

RESUMO

Water collection from atmospheric fog was deemed to be an efficient and sustainable strategy to defuse the freshwater scarcity crisis. Fog harvesting and trapping fibers, therefore, has aroused extensive interest due to their ease of preparation, weave, and use. However, the traditional fibers used in fog collector usually have a low fog collection capacity and efficiency because of their unreasonable morphology and structure design. Herein, we proposed a simple process to construct advanced fibers using a one-step wet spinning of hydrophobic polyvinylidene fluoride (PVDF) and hydrophilic cellulose mixture fiber for fog harvesting. The as-prepared fibers featured a petaloid structure and surface hydrophobic gradient, thus facilitating fog deposition, water droplet formation, and drainage. The unique longitudinal groove structure above enabled the hybrid fiber to achieve an excellent fog collection efficiency of 2750.26 mg/cm2/h per monofilament, which outstripped most of other fiber materials. When woven these fibers were in a longitudinal array network with an interval of 1 mm, and the fog collection efficiency can maintain at 10.30 L/m2/h. Therefore, this work provided a new strategy for further exploration of effective fog collection by cellulose-based fiber materials.

16.
Int J Biol Macromol ; 274(Pt 2): 133280, 2024 Jun 20.
Artigo em Inglês | MEDLINE | ID: mdl-38908622

RESUMO

Electromagnetic hydrogels have attracted significant attention due to their vast potential in soft robotics, biomedical engineering, and energy harvesting. To facilitate future commercialization via large-scale industrial processes, we present a facile concept that utilizes the specialized knowledge of papermaking to fabricate hydrogels with multifunctional electromagnetic properties. The principles of papermaking wet end chemistry, which involves the handling of interactions among cellulosic fibers, fines, polymeric additives, and other components in aqueous systems, serves as a key foundation for this concept. Notably, based on these principles, the versatile use of chemical additives in combination with cellulosic materials enables the tailored design of various products. Our methodology exploits the unique hierarchically pitted and hollow tube-like structures of papermaking grade cellulosic fibers with discernible pits, enabling the incorporation of magnetite nanoparticles through lumen loading. By combining microscale softwood-derived cellulosic fibers with additives, we achieve dynamic covalent interactions that transform the cellulosic fiber slurry into an impressive hydrogel. The cellulosic fibers act as a skeleton, providing structural support within the hydrogel framework and facilitating the dispersion of nanoparticles. In accordance with our concept, the typical hydrogel exhibits combined attributes, including electrical conductivity, self-healing properties, pH responsiveness, and dynamic rheologic behavior. Our approach not only yields hydrogels with interesting properties but also aligns with the forefront of advanced cellulosic material applications. These materials hold the promise in remote strain sensing devices, electromagnetic navigation systems, contactless toys, and flexible electronic devices. The concept and findings of the current work may shed light on materials innovation based on traditional pulp and paper processes. Furthermore, the facile processes involved in hydrogel formation can serve as valuable tools for chemistry and materials education, providing easy demonstrations of principles for university students at different levels.

17.
Chem Commun (Camb) ; 60(9): 1193, 2024 Jan 25.
Artigo em Inglês | MEDLINE | ID: mdl-38214682

RESUMO

Correction for 'Critical role of hydrogen bonding between microcrystalline cellulose and g-C3N4 enables highly efficient photocatalysis' by Zhaoqiang Wang et al., Chem. Commun., 2024, 60, 204-207, https://doi.org/10.1039/D3CC04800D.

18.
Carbohydr Polym ; 334: 122035, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38553204

RESUMO

Inspired from human skin, micro- and nano-wrinkled wood surface with skin-tactile performance was designed and developed using a waterborne UV-curable polyurethane acrylate coating and cellulose nofibers (CNF). To further improve the properties, the CNF was diacetylated to D-CNF and further grafted with a hyperbranched polymer containing rich end amino groups (HB-CNF). The surface structure and chemical reactions were characterized, and the skin-tactile performance of the coating was comprehensively investigated. The HB-CNF exhibited excellent dispersion in the coating, and extensive reactions occurred between the two through the -NH2 and terminal -NCO groups, resulting in much improved mechanical properties and durability. Micro-wrinkles with a width of approximately 12-15 µm and a height of 8-14 µm were created, and nano-protrusions of wrinkles ranging from to 50-100 nm were obtained. The coated surface was hydrophobic and exhibited high resilience after compression, with a gloss of 3.3 GU at an incident angle of 60° and a static friction coefficient of 0.26, both of which were similar to those of human skin. The results presented an effective strategy for high-performance wood products with a good feeling, which is helpful to improve the market competitiveness and meet the people's pursuit of a better life.

19.
Adv Sci (Weinh) ; 11(11): e2305962, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38161220

RESUMO

Personalized healthcare management is an emerging field that requires the development of environment-friendly, integrated, and electrochemical multimodal devices. In this study, the concept of integrated paper-based biosensors (IFP-Multi ) for personalized healthcare management is introduced. By leveraging ink printing technology and a ChatGPT-bioelectronic interface, these biosensors offer ultrahigh areal-specific capacitance (74633 mF cm-2 ), excellent mechanical properties, and multifunctional sensing and humidity power generation capabilities. More importantly, the IFP-Multi devices have the potential to simulate deaf-mute vocalization and can be integrated into wearable sensors to detect muscle contractions and bending motions. Moreover, they also enable monitoring of physiological signals from various body parts, such as the throat, nape, elbow, wrist, and knee, and successfully record sharp and repeatable signals generated by muscle contractions. In addition, the IFP-Multi devices demonstrate self-powered handwriting sensing and moisture power generation for sweat-sensing applications. As a proof-of-concept, a GPT 3.5 model-based fine-tuning and prediction pipeline that utilizes recorded physiological signals through IFP-Multi is showcased, enabling artificial intelligence with multimodal sensing capabilities for personalized healthcare management. This work presents a promising and ecofriendly approach to developing paper-based electrochemical multimodal devices, paving the way for a new era of healthcare advancements.


Assuntos
Dispositivos Eletrônicos Vestíveis , Humanos , Inteligência Artificial , Atenção à Saúde , Tinta , Impressão
20.
Food Chem ; 453: 139673, 2024 Sep 30.
Artigo em Inglês | MEDLINE | ID: mdl-38772308

RESUMO

Herein, the nanolignin-containing cellulose nanofibrils (LCNF)-enabled ratiometric fluorescent bio-nanocomposite film is developed. Interestingly, the inclusion of LCNF in the cellulose-based film enhances the detecting performance of food freshness, such as high sensitivity to biogenic amines (BAs) (limit of detection (LOD) of up to 1.83 ppm) and ultrahigh discernible fluorescence color difference (ΔE = 113.11). The underlying mechanisms are the fluorescence resonance energy transfer (FRET), π - π interaction, and cation - π interaction between LCNF and fluorescein isothiocyanate (FITC), as well as the increased hydrophobicity due to lignin, which increases the interactions of amines with FITC. Its color stability (up to 28 days) and mechanical property (49.4 Mpa) are simultaneously improved. Furthermore, a smartphone based detecting platform is developed to achieve access to food safety. This work presents a novel technology, which can have a great potential in the field of food packaging and safety.


Assuntos
Celulose , Embalagem de Alimentos , Nanocompostos , Nanofibras , Celulose/química , Embalagem de Alimentos/instrumentação , Nanofibras/química , Nanocompostos/química , Transferência Ressonante de Energia de Fluorescência , Aminas Biogênicas/análise , Aminas Biogênicas/química , Fluorescência
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