Large magnetic anisotropy enhancement in size controlled Ni nanowires electrodeposited into nanoporous alumina templates.

A large enhancement of the magnetic anisotropy of Ni nanowires (NWs) embedded in anodic aluminium oxide porous membranes is obtained as a result of an induced magnetoelastic (ME) anisotropy contribution. This unusual large anisotropy enhancement depends on the diameter of the NWs and exceeds the magnetostatic (MS) contribution. As a consequence, it leads to effective magnetic anisotropy energies as large as 1.4 × 10(6) erg cm(-3), which are of the same order of magnitude and comparable to the MS energies of harder magnetic materials like Co NWs. Specifically, from ferromagnetic resonance experiments, the magnetic anisotropy of the NWs has been observed to increase as its diameter is decreased, leading to values that are about four times larger than the corresponding value when only the MS anisotropy is present. Our results are consistent with the recently proposed growth mechanism of Ni NWs that proceeds via a poly-crystalline stage at the bottom followed by a single-crystalline stage with texture [110] parallel to the axis of the NWs. A strong correlation between reducing the diameter of the NWs with the decrease of the length of the poly-crystalline segment and the enhancement of the effective magnetic anisotropy has been shown. Magnetization curves obtained from alternating gradient magnetometry experiments show that the average ME anisotropy results from the competition between the magnetic anisotropies of both crystalline segments of the NWs. Understanding the influence of size and confinement effects on the magnetic properties of nanocomposites is of prime interest for the development of novel and agile devices.

Magnetic force microscopy investigation of arrays of nickel nanowires and nanotubes.

The magnetic properties of arrays of nanowires (NWs) and nanotubes (NTs), 150 nm in diameter, electrodeposited inside nanoporous polycarbonate membranes are investigated. The comparison of the nanoscopic magnetic force microscopy (MFM) imaging and the macroscopic behavior as measured by alternating gradient force magnetometry (AGFM) is made. It is shown that MFM is a complementary technique that provides an understanding of the magnetization reversal characteristics at the microscopic scale of individual nanostructures. The local hysteresis loops have been extracted by MFM measurements. The influence of the shape of such elongated nanostructures on the dipolar coupling and consequently on the squareness of the hysteresis curves is demonstrated. It is shown that the nanowires exhibit stronger magnetic interactions than nanotubes. The non-uniformity of the magnetization states is also revealed by combining the MFM and AGFM measurements.

Artificial vortex pinning arrays in superconducting films deposited on highly ordered anodic alumina templates.

A simple procedure is described for creating periodic vortex pinning centers in thin superconducting NbN films. We report on three different strategies which involve the use of highly ordered alumina templates. In this approach, NbN thin films are deposited either on the porous face of the template made of a triangular array of nanoholes or on the triangular array of bumps formed by the barrier layer or even on the top of perpendicularly oriented ferromagnetic nanowire arrays obtained by electrochemical deposition, thus forming superconductor-ferromagnet hybrids. In all cases, the ordered template allows NbN films to form a periodic pinning array during its growth. The interpore (or inter-bump) distance ranged between 50 and 100 nm and adjustable pore (or wire) diameter was varied between 30 and 60 nm. Numerous matching effects have been observed up to 2.5 T and are maintained at low temperature. These fields are considerably higher than those typical for periodic pinning arrays made by lithographic techniques, which reflects the benefits of nanostructuring superconductors by using self-organized growth to enhance vortex pinning in a large field and temperature range.

Imprinting nanoporous alumina patterns into the magneto-transport of oxide superconductors.

We used oxygen ion irradiation to transfer the nanoscale pattern of a porous alumina mask into high-T(C) superconducting thin films. This causes a nanoscale spatial modulation of superconductivity and strongly affects the magneto-transport below T(C), which shows a series of periodic oscillations reminiscent of the Little-Parks effect in superconducting wire networks. This irradiation technique could be extended to other oxide materials in order to induce ordered nanoscale phase segregation.

Microwave circulator based on ferromagnetic nanowires in an alumina template.

Unbiased planar microwave circulators were fabricated by electrodeposition of NiFe nanowires into porous alumina templates. Microwave properties of the devices are seen to depend drastically on the height of the nanowires and the newly developed devices exhibit improved features, compared to existing nanowire-based designs. Thanks to the high anisotropy of the nanowires, zero-field circulation modes may be observed in a frequency range from 10 to 30 GHz, with isolation as large as 30 dB, as well as low insertion losses - 5 dB, making it compatible with industrial needs for device applications.

Relation of the average interaction field with the coercive and interaction field distributions in First order reversal curve diagrams of nanowire arrays.

First-order reversal curve diagrams, or FORC diagrams, have been studied to determine if the widths of their distributions along the interaction and coercivity axes can be related to the mean-field magnetization dependent interaction field (MDIF). Arrays of nanowires with diameters ranging from 18 up to 100 nm and packing fractions varying from 0.4 to 12% have been analyzed. The mean-field MDIF has been measured using the remanence curves and used as a measuring scale on the FORC diagrams. Based on these measurements, the full width of the interaction field distribution and the full width at half maximum (FWHM) of the FORC distribution profile along the interaction field direction are shown to be proportional to the MDIF, and the relation between them is found. Moreover, by interpreting the full width of the coercive field distribution in terms of the dipolar induced shearing, a simple relation is found between the width of this distribution and the MDIF. Furthermore, we show that the width of the FORC distribution along the coercive field axis is equal to the width of the switching field distribution obtained by the derivation of the DC remanence curve. This was further verified with the switching field distribution determined using in-field magnetic force microscopy (MFM) for very low density nanowires. The results are further supported by the good agreement found between the experiments and the values calculated using the mean-field model, which provides analytical expressions for both FORC distributions.

Electroless template grown superconducting lead and tin nanotubes.

Lead and tin nanotubes were synthesized by electroless deposition in a nanoporous polymer membrane without sensitization, activation or a reducing agent. A thick Pb or Sn layer is evaporated on one side of the membrane and provides the metallic ions needed to grow the tubes in an aqueous solution. The nanotubes' geometry and composition were investigated by means of electron microscopy, energy dispersive x-ray spectroscopy and ultramicrotomy. Electrical measurements obtained on such superconducting nanotubes are compared with solid wire characteristics. This spontaneous growth could explain some recent results obtained on superconducting nanowires showing an anomalous long-range proximity effect.

Magnetic and superconducting nanowires.

This article is focused on the use of electrodeposition and of various nanoporous templates for the fabrication of metallic nanowires made from single metals (Ni, Co, Pb, Sn), alloys (NiFe, CoFe, CoPt), and multilayers (Co/Cu, NiFe/Cu). An overview is given of our recent studies performed on both magnetic and superconducting nanowires. Using different approaches entailing measurements on both single wires and arrays, numerous interesting physical properties have been identified in relation to the nanoscopic dimensions of these materials. Finally, various novel applications of the nanowires are also discussed.

Spin accumulation and domain wall magnetoresistance in 35 nm Co wires

An enhancement of the resistance due to the presence of only one or two isolated domain walls is clearly evidenced by transport measurements in 35 nm epitaxial Co wires, 20 &mgr;m long. The deduced relative change in the resistivity is at least 1 order of magnitude larger than the one predicted from a model based on the mixing of spin channels occurring over the length scale of the domain wall width [P. M. Levy and S. Zhang, Phys. Rev. Lett. 79, 5110 (1997)]. This inconsistency can be resolved by taking the effect of spin accumulation into account, which scales in the case of Co over the much larger distance of the spin diffusion length.

Dipolar interaction in arrays of magnetic nanotubes.

The dipolar interaction field in arrays of nickel nanotubes has been investigated on the basis of expressions derived from the effective demagnetizing field of the assembly as well as magnetometry measurements. The model incorporates explicitly the wall thickness and aspect ratio, as well as the spatial order of the nanotubes. The model and experiment show that the interaction field in nanotubes is smaller than that in solid nanowires due to the packing fraction reduction in tubes related to their inner cavity. Finally, good agreement between the model and experiment is found for the variation of the interaction field as a function of the tube wall thickness.

Configuration dependent demagnetizing field in assemblies of interacting magnetic particles.

A mean field model is presented for the configuration dependent effective demagnetizing and anisotropy fields in assemblies of exchange decoupled magnetic particles of arbitrary shape which are expressed in terms of the demagnetizing factors of the particles and the volumetric shape containing the assembly. Perpendicularly magnetized two-dimensional (2D) assemblies have been considered, for which it is shown that the demagnetizing field is lower than the continuous thin film. As an example of these 2D systems, arrays of bistable cylindrical nanowires have been characterized by remanence curves as well as ferromagnetic resonance, serving to show the correspondence of these measurements with the model and also to validate the mean field approach. Linear chains of cylinders and spheres have been analyzed, leading to simple expressions to describe the easy axis rotation induced by the interaction field in chains of low aspect ratio cylindrical particles, and the dipolar magnetic anisotropy observed in the linear chain of spheres. These examples serve to underline the dependence on the dipolar interaction field and effective demagnetizing factor of the contributions that arise from the shape of the outer volume.