RESUMO
Single-atom catalysts have been touted as highly efficient catalysts, but the catalytic single-atom sites are unstable and tend to aggregate into nanoparticles during chemical reactions. In this study, we show that SiC monolayers are promising substrates for the development of highly stable single-atom catalysts (Pd1 /SiC) within the density functional theory. In presence of a Si-vacancy, the diffusion barrier energy of a Pd1 atom embedded in the SiC monolayer is substantially enhanced from 2.3 to 7.8â eV, which is much higher than the reported diffusion barrier energies of graphene, boron nitride and defective MgO of the same catalytic system. Ab initio molecular dynamic calculations at 500â K also confirm the enhanced stability of Pd1 /SiC monolayer (Si-vacancy) such that the Pd1 atom remains embedded in the vacancy. Additionally, the Pd1 /SiC monolayer (Si-vacancy) catalysts show a â¼34 % reduction of activation barrier energy for CO oxidation as compared to pristine catalysts. This work implies that nanostructured SiC materials are promising substrates for the synthesis of highly stable single-atom catalysts.
RESUMO
Rh-Fe catalysts supported on Ca-Al2O3, MgO and ZrO2 were evaluated in ethanol steam reforming at 623 K and compared to Rh catalysts on the same supports without iron promotion. The metal-support interaction among the three entities, i.e. Rh â Fe2O3 â support (ZrO2, MgO and Ca-Al2O3) was investigated using H2-chemisorption, TEM, XPS and in situ techniques such as DRIFTS, temperature-resolved XRD and XAS. As compared to the unpromoted Rh catalysts on the same supports, the CO selectivity is depressed in the presence of iron on Rh/MgO and Rh/Ca-Al2O3, the latter being significantly superior. The role of metal-support interaction for CO-free hydrogen generation was unravelled using a combination of techniques. It was found that the reducibility of iron oxide determines the extent of the strong metal support interaction between Rh and Fe2O3 and the reducibility of iron oxide was affected by the support. On Rh-Fe/Ca-Al2O3, a good balance of the interaction between Rh, Fe2O3 and Ca-Al2O3 prevents strong metal support interaction between Rh and Fe2O3 and thus promotes CO elimination via water-gas-shift reaction on Rh-FexOy sites.