Pristine and biochar-supported nano zero-valent iron to immobilize As, Zn and Pb in soil contaminated by smelting activities.

Nano zero-valent iron (nZVI) is one of the most studied nanomaterials for environmental remediation during the past 20 years. However, few studies have focused on nZVI combination with other materials (e.g., biochar) for enhancement of soil remediation. In this study, pristine nZVI and a composite of wood sawdust biochar (BC) and nZVI (nZVI-BC) were added to a highly contaminated soil to compare their efficacy in immobilizing available arsenic (As = 28.6 mg kg-1), zinc (Zn = 1707 mg kg-1), and lead (Pb = 6759 mg kg-1). Sediment quality guidelines were used to evaluate the extent of soil contamination and ascertain its source. The mineralogy of soil and slags were assessed by X-ray Diffractometry Spectroscopy (XRD), and the geochemical fractions of Pb, Zn, and As were obtained by chemical sequential extractions. The average Pollution Load Index (PLI) was 10.66, indicating elevated multi-elemental contamination. Contamination Factor (CF) values for As, Zn, Pb, cadmium (Cd), and copper (Cu) were all higher than 6 which implies extreme contamination. Secondary minerals frequently found in Pb/Zn smelter sites, such as cerussite and anglesite, were detected in the slags through XRD. Pb and Zn were mainly bound to carbonates and residual fractions in soil and presented a high risk considering the sediment quality guidelines, sequential extraction results, and XRD analysis. The treatment with nZVI-BC was more effective than pristine nZVI on concurrently decreasing 97% of available As, 84% of Pb and 81% of Zn compared to control. The application of nZVI-BC is a promising green and sustainable remediation technique for soils contaminated with potentially toxic elements of distinct chemical behavior.

Effect of selenium and soil pH on cadmium phytoextraction by Urochloa decumbens grown in Oxisol.

It has been speculated that selenium (Se) supply can affect cadmium (Cd) 'availability' and increase the Cd tolerance of plants used for phytoextraction, in a pH-dependent process. Thus, we evaluated the interaction Cd-Se and the effects of soil pH in this interaction on plant availability of Cd and phytoextraction efficiency of Urochloa decumbens cv. Basilisk grown in Oxisol. Two soil concentrations of Cd (0.93 and 3.6 mg kg-1) and Se (<0.2 and 1 mg kg-1) and two soil pH (0.01 mol L-1 CaCl2) conditions (4.1 and 5.7) were considered. At both pH, Se supply increased the exchangeable fraction of Cd and decreased the residual Cd fraction. At pH 4.1, the growth of U. decumbens was impaired by Se addition, regardless of Cd exposure. The lower root growth and tillering of U. decumbens exposed to Cd disappeared at pH 5.7 due to uptake of low Se concentrations. Thus, the toxic or beneficial effects of Se on growth of U. decumbens used for Cd phytoextraction depend on the amount of Se assimilated. The Cd phytoextraction efficiency of U. decumbens was not improved by Se supply, regardless of soil pH. Therefore, we cannot recommend the application of Se to increase Cd phytoextraction by this grass.

Temporal changes in arsenic and lead pools in a contaminated sediment amended with biochar pyrolyzed at different temperatures.

Globally, tons of soils and sediments are experiencing degradation due to the presence of high concentrations of potentially toxic elements (PTEs), such as arsenic (As) and lead (Pb), in areas in the vicinity of metal mining activities. The addition of biochar to contaminated sediments is a promising in situ remediation approach, and the effects of pyrolysis temperature and biochar aging are important factors for the immobilization and fate of PTEs. In this study, we evaluated the temporal changes in pools of As and Pb in sediment amended with biochars produced from sugarcane (Saccharum officinarum) pyrolyzed at 350 (BC350), 550 (BC550), and 750 °C (BC750). Biochars were aged by natural process (without additional acid or heat), and changes in As and Pb pools were evaluated every 45 days until completing 180 days of incubation. Changes in the As and Pb pools were extracted with water (bioavailable), magnesium chloride (exchangeable), nitric acid (active geochemical fraction), and exchangeable Mehlich-3 (associated with organic matter). As and Pb available contents have increased over time. BC750 was more effective in reducing the bioavailable and exchangeable As contents, while BC550 and BC350 were more effective in reducing the contents of bioavailable and exchangeable Pb.