A biodegradable composite filter made from electrospun zein fibers underlaid on the cellulose paper towel.

Conventional petroleum-based synthetic polymeric fiber filter materials for separation may cause secondary pollution to the environment due to their non-degradable properties. Herein, we report a facile method of preparation of a biodegradable composite filter that can achieve filtration for air by underlaying the commercialized cellulose paper towel under electrospun zein fibers. The morphology of zein fibers was successfully steered via varying the weight ratios of ethanol/deionized water mixture solvent, as a result, the round or flat ribbon fibers were obtained. The effect of zein fiber morphology on air filtration performance was investigated both experimentally and theoretically. It was found that the flat ribbon fiber filter had a higher filtration efficiency (99%) for PM0.3 removal and a lower pressure drop (109 Pa) compared with the round zein fiber filter. Notably, the as-prepared composite filter can be biodegradable easily, contributing to green ecological environment. This work shows an efficient way to develop biodegradable filtration materials with the cheap price, easy availability of component materials, exhibiting a great potential application in air filtration area.

Nanocellulose implantation enriched the pore structure of aerogel for effective particulate matter removal.

Particulate matter (PM) pollution poses a serious threat to public health, disposable and degradable filter materials are expected to handle the problem in the future. Here, polyvinyl alcohol (PVA)/borax/cellulose nanofibrils (CNF) aerogels were implanted on a biodegradable corrugated paper to form composite air filters for the first time via freeze-drying the coated composite hydrogels. The low content of CNF and PVA could be cross-linked by borax to form hydrogels, which enhanced its maneuverability for surface implanting on the substrate. More importantly, the addition of CNF greatly enriched the pore structure of aerogels, which provided a structural basis for PM capture. The as-prepared composite air filters exhibited excellent filtration efficiencies of 92 % and 96 % toward PM1.0 and PM3.0, respectively. Moreover, the addition of dimethylol-5,5-dimethylhydantoin endowed the filters with an antibacterial property. This work shows a new possibility for the design of degradable and functional filter materials.

Hierarchically Structured Nanocellulose-Implanted Air Filters for High-Efficiency Particulate Matter Removal.

Fine particulate matter (PM) air pollution has increasingly become a global problem; thus, high-performance air filtration materials are in great demand. Herein, we first prepared a biodegradable hierarchically structured nanocellulose-implanted air filter with a high filtration capacity using a freeze-drying technique. In this hierarchically structured air filter, porous structures of corrugated paper and cellulose nanofibrils (CNFs) were used as a frame and functional fillers, respectively. The self-assembled structure of the CNF fillers could be controlled by changing the freezing temperature, CNF sizes, concentrations, and base weights. Only the CNFs with a smaller size and concentration of 0.05 wt % were able to self-assemble to well-dispersed fibril networks. With constant optimization of conditions, when the base weight went up to only 0.25 g/m2, the coverage of the corrugated paper fibers with CNF networks became perfect, and a high efficiency of 94.6% for PM0.3 removal was achieved, while maintaining a relatively low pressure drop of 174.2 Pa. All of the raw materials we used are biodegradable, nonpetroleum-based materials, contributing to sustainable development. We believe that such excellent biodegradable high-performance cellulose-based air filtration materials will provide a new direction for the application of nanocellulose in air filtration.