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1.
Int J Aging Hum Dev ; : 914150241235086, 2024 Feb 27.
Artigo em Inglês | MEDLINE | ID: mdl-38414341

RESUMO

Objectives: The purpose of this study was to translate and validate the adolescents' ageism toward older adults scale (AGES) in the Chinese cultural context and examine its psychometric properties among Chinese adolescents. Methods: The study consists of two phases with two separate samples. In phase one (sample 1: n = 407), exploratory factor analysis (EFA) is conducted to determine the factor structure of the C-AGES. In phase two (sample 2: n = 379), confirmatory factor analysis (CFA) is performed to confirm the factor structure and assess the model fit of the C-AGES. Results: EFA reveals a two-factor structure consisting of 17 items for the C-AGES. CFA in sample 2 confirms the factor structure and demonstrates good model fit. The C-AGES also exhibits high criterion validity, internal consistency, and cross-gender invariance. Discussion: The results suggest that the C-AGES is a valid measurement tool for assessing agism among Chinese adolescents.

2.
Mol Biol Evol ; 39(1)2022 01 07.
Artigo em Inglês | MEDLINE | ID: mdl-34718707

RESUMO

Evolutionary radiation is a widely recognized mode of species diversification, but its underlying mechanisms have not been unambiguously resolved for species-rich cosmopolitan plant genera. In particular, it remains largely unknown how biological and environmental factors have jointly driven its occurrence in specific regions. Here, we use Rhododendron, the largest genus of woody plants in the Northern Hemisphere, to investigate how geographic and climatic factors, as well as functional traits, worked together to trigger plant evolutionary radiations and shape the global patterns of species richness based on a solid species phylogeny. Using 3,437 orthologous nuclear genes, we reconstructed the first highly supported and dated backbone phylogeny of Rhododendron comprising 200 species that represent all subgenera, sections, and nearly all multispecies subsections, and found that most extant species originated by evolutionary radiations when the genus migrated southward from circumboreal areas to tropical/subtropical mountains, showing rapid increases of both net diversification rate and evolutionary rate of environmental factors in the Miocene. We also found that the geographically uneven diversification of Rhododendron led to a much higher diversity in Asia than in other continents, which was mainly driven by two environmental variables, that is, elevation range and annual precipitation, and were further strengthened by the adaptation of leaf functional traits. Our study provides a good example of integrating phylogenomic and ecological analyses in deciphering the mechanisms of plant evolutionary radiations, and sheds new light on how the intensification of the Asian monsoon has driven evolutionary radiations in large plant genera of the Himalaya-Hengduan Mountains.


Assuntos
Rhododendron , Ásia , Evolução Biológica , Filogenia , Plantas , Rhododendron/genética
3.
Water Environ Res ; 91(5): 455-461, 2019 May.
Artigo em Inglês | MEDLINE | ID: mdl-30740828

RESUMO

Eutectic freeze crystallization was developed to recover sodium erythorbate (NaE) from wastewater at pHs 4.1, 5.3, and 6.5. Two substances (A and B) were sequentially recovered from the samples. The recovery rate of substance A was 2.06, 1.83, and 3.03 g/L at pHs 4.1, 5.3, and 6.5, respectively; while that of B was 5.51, 3.09, and 3.26 g/L at the corresponding pHs. The analysis results of the two recovered substances indicated that substance A was mostly Na2 SO4 ·10H2 O, while substance B was mainly NaE. Salt recovery was most successful at pH 4.1 with the purity of recovered NaE reaching 87.53 wt%. Moreover, the chemical oxygen demand and electric conductivity of the ice were far smaller than the initial wastewater. The concentration effect was minimal due to the formation of Na2 SO4 ·10H2 O and NaE crystals. This combined crystallization strategy can potentially become an economic technology to recover NaE from wastewater. Practitioner points Segregation of NaE and Na2 SO4 ·10H2 O during the freeze crystallization process. Recovering 5.53 kg NaE with the purity of 87.53 wt% from 1 m3 wastewater. Decreasing chemical oxygen demand and electric conductivity of wastewater through freeze crystallization technology.


Assuntos
Ácido Ascórbico/química , Ácido Ascórbico/isolamento & purificação , Congelamento , Águas Residuárias/química , Poluentes Químicos da Água/química , Poluentes Químicos da Água/isolamento & purificação , Purificação da Água/métodos , Cristalização , Concentração de Íons de Hidrogênio , Gelo/análise , Fatores de Tempo
4.
Bioprocess Biosyst Eng ; 39(10): 1627-34, 2016 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-27282165

RESUMO

A rotating disk electrode (RDE) was used to investigate the concentration loss and impedance characteristics of anodic biofilms in microbial fuel cells (MFCs). Amperometric time-current analysis revealed that at the rotation rate of 480 rpm, a maximum current density of 168 µA cm(-2) can be achieved, which was 22.2 % higher than when there was no rotation. Linear sweep voltammetry and electrochemical impedance spectroscopy tests showed that when the anodic potential was set to -300 mV vs. Ag/AgCl reference, the power densities could increase by 59.0  %, reaching 1385 mW m(-2), the anodic resistance could reduce by 19  %, and the anodic capacitance could increase by 36 %. These results concur with a more than 85 % decrease of the diffusion layer thickness. Data indicated that concentration loss, diffusion layer thickness, and the mixing velocity play important roles in anodic resistance reduction and power output of MFCs. These findings could be helpful to the design of future industrial-scale MFCs with mixed bacteria biofilms.


Assuntos
Fenômenos Fisiológicos Bacterianos , Fontes de Energia Bioelétrica/microbiologia , Biofilmes , Impedância Elétrica , Eletrodos
5.
Bioprocess Biosyst Eng ; 38(7): 1325-33, 2015 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-25656699

RESUMO

It is known that cell potential increases while anode resistance decreases during the start-up of microbial fuel cells (MFCs). Biological capacitance, defined as the apparent capacitance attributed to biological activity including biofilm production, plays a role in this phenomenon. In this research, electrochemical impedance spectroscopy was employed to study anode capacitance and resistance during the start-up period of MFCs so that the role of biological capacitance was revealed in electricity generation by MFCs. It was observed that the anode capacitance ranged from 3.29 to 120 mF which increased by 16.8% to 18-20 times over 10-12 days. Notably, lowering the temperature and arresting biological activity via fixation by 4% para formaldehyde resulted in the decrease of biological capacitance by 16.9 and 62.6%, indicating a negative correlation between anode capacitance and anode resistance of MFCs. Thus, biological capacitance of anode should play an important role in power generation by MFCs. We suggest that MFCs are not only biological reactors and/or electrochemical cells, but also biological capacitors, extending the vision on mechanism exploration of electron transfer, reactor structure design and electrode materials development of MFCs.


Assuntos
Fontes de Energia Bioelétrica , Espectroscopia Dielétrica/instrumentação , Eletrodos , Temperatura
6.
Guang Pu Xue Yu Guang Pu Fen Xi ; 35(5): 1153-8, 2015 May.
Artigo em Zh | MEDLINE | ID: mdl-26415418

RESUMO

The solution of ion mobility's nonlinear function coefficients α2 and α4 is the basis for achieving substance identification of High Field Asymmetric waveform Ion Mobility Spectrometry (FAIMS). Currently, nonlinear function coefficients α2 and α4 lack priors, meanwhile, existed solving results about α2 and α4 are deficient in error evaluation standard. In this article, acetone, isopropanol and 1, 2-dichlorobenzene were detected under different dispersion voltage by homemade FAIMS. In general, the spectrum peak of same sample at different dispersion voltage value is unique. Different dispersion voltage and corresponding compensation voltage value determines the value of α2 and α4. According to sample spectra at different dispersion voltage value, groups of spectral characteristics were obtained. Affirmatory number of data which were selected from multiple sets of compensation voltage value and dispersion voltage value, so that they were utilized to solved out lots of α2 and α4. Lots of factor have an effect on the accuracy of the solving results of α2 and α4, for instance, value of compensation voltage and dispersion voltage, style of fetching points of dispersion voltage, and so on. Comparing to other factors, style and amount of dispersion voltage is likely to control. By data analyzing huge amounts of α2 and α4 data, this paper explored their characteristic of distribution and correlation about them, research influence of number and method to fetch dispersion voltage detected points for error of solving results. After fitting frequency of α2 and α4, it was found that they conform to normal distribution, goodness of fitting exceed 0. 96, thus standard deviation of their distribution are able to evaluate error of solving results. In addition, a strong correlation exists between them, relevance of sample is -0. 977, -0. 968, -0. 992 respectively. With increasing of computing selected points, the corresponding error of solving results decrease. By comparing the standard deviation of method to fetch dispersion voltage detected points, found that detecting frequency in case of detecting maximum and the 70% of maximum of dispersion voltage value is lower at approximately same standard deviation, solving effect was optimized in unique fetching points style. Based on the premise of ensuring the accuracy of solving results of α2 and α4, it is obvious that reducing the frequency of detections for FAIMS effectively. It created favorable conditions for rapid field detection and precise spectral analysis.

7.
Sci Total Environ ; 926: 171942, 2024 May 20.
Artigo em Inglês | MEDLINE | ID: mdl-38527553

RESUMO

Wastewater reclaim in industrial parks can effectively reduce the dependence on external water resources, few literatures evaluated the reclaim system from perspectives of economy, technology, and environmental impact. It is very popular across China that a constructed wetland is linked with a wastewater plant and then discharged the tailwater into surface waters, based on current situation, pilot experiment, and other available techniques, six scenarios for wastewater reclaim system were designed for Shanghai Chemical Industrial Park. Using life cycle assessment, it was found that in scenario of pilot experiment, most environmental impact was derived from wastewater plant and ultra filtration - reverse osmosis, in which ultra filtration - reverse osmosis accounted >20 % for POCP, AP, and EP, Wastewater plant accounted >86 % for ADP, ODP. It was showed that electricity and sludge were most important parameters affecting LCA, when electricity consumption was reduced by 20 %, total standardized environmental impact would be changed in the range of 1.40 %-1.65 %, the most significant change was HTP (6.12 %-6.32 %) when 20 % up and downward change in sludge amount, followed by MAETP (5.27 %-5.36 %). A multi-criteria decision-making analysis was conducted on all the scenarios based on environmental impact, life cycle cost, technical efficiency, it was showed that the scenario designed for pilot experiment was the best available technique, which was consisted of wastewater plant, hybrid constructed wetland, ultra-filtration and reverse osmosis, and reused as desalted water. A wastewater reclaim plant is suggested from the result of this paper. It was believed that this study could provide references for construction of wastewater reclaim system in industrial parks of the world.

8.
Environ Technol ; 34(1-4): 269-74, 2013.
Artigo em Inglês | MEDLINE | ID: mdl-23530340

RESUMO

This work focused on studying the effect of the chemical oxidation demand to sulfide ratio (COD/S) on power generation and sulfide oxidation in microbial fuel cells treating sulfide-rich wastewater containing organic contaminants. The maximum power density achieved was 20 +/- 1 W m(-3) V(Anode) and the C(oulombic) yield was 20 +/- 2%. The COD/S ofinfluent played an important role in elemental sulfur and sulfate production because of competition between acetate oxidation and element sulfur oxidation to sulfate in the anode. When the COD/S was 12.50/1, more than 74.0% of sulfide was converted into elemental sulfur after 24 hours of operation. The effect of the COD/S on power generation was negligible when the COD/S ranged between 4.85/l and 18.53/l. After 24 hours, the COD removals were 110 +/- 6, 213 +/- 9, 375 +/- 8 and 410 +/- 10 mgl(-1) when the COD/S was 4.85/1, 8.9/1, 12.5/1 and 18.53/1, respectively. The COD removal increased with the increasing COD of the influent, which fitted to the model of first-order reaction kinetics.


Assuntos
Fontes de Energia Bioelétrica , Sulfetos/química , Águas Residuárias/química , Análise da Demanda Biológica de Oxigênio , Temperatura Baixa , Desinfetantes , Transferência de Energia , Fontes Geradoras de Energia , Microscopia Eletrônica de Varredura , Oxirredução
9.
Front Psychol ; 14: 1279853, 2023.
Artigo em Inglês | MEDLINE | ID: mdl-38162965

RESUMO

The act of self-praise, a novel and prevalent discourse pattern on social media across different cultures, is still understudied. As such, this study delves into self-praise from linguistic and psychological perspectives by examining and comparing the strategies, themes, and motivations of self-praise on English and Chinese social media. A discourse-based analysis of the data comprising 200 posts from Twitter (English) users and 200 posts from Weibo (Chinese) users revealed that Twitter users favored more unmodified explicit self-praise strategies, while Weibo users opted for more implicit self-praise strategies. Both groups employed explicit self-praise equally, but with different sub-strategies. The most prevalent themes were appearance, competence/performance, skills, virtues, and self-encouragement. Appearance was more dominant among Twitter users, whereas skills and self-encouragement were more popular among Weibo users. Both groups valued competence/performance and virtues, but with different virtues. Twitter users valued cherishing friendship, bravery, and maturity, whereas Weibo users stressed kindness, cherishing kinship, and thoughtfulness. Two semi-structured interviews conducted with six Twitter participants and six Weibo participants indicated that the motivations for online self-praise in both groups were psychological needs such as self-flattery, self-presentation, and self-encouragement, while commercial profit was a motivation only for Weibo participants. This study also discusses the social and cultural factors that may account for these differences and provides implications for future research on online self-praise.

10.
Sci Total Environ ; 866: 161310, 2023 Mar 25.
Artigo em Inglês | MEDLINE | ID: mdl-36603642

RESUMO

Although sodium hypochlorite acting as an oxidant has been investigated for the role it plays in the degradation of organic contaminants, little attention has been paid to its activation and efficient utilization. In this study, natural manganese sand (NMS) was verified to be effective for activation of sodium hypochlorite (NaClO). Due to the generation of O2-, the removal efficiency of ionic organic contaminants in NMS/NaClO system was 1.9-4.1 times higher than that in NMS or NaClO alone. Hence, NMS activated NaClO system performed ~96.6 % contaminants removal efficiency at a wide pH range (pH 5-9). Kinetic modeling yielded that the NMS dosage was more important than NaClO dosage. Long-term stability was observed in the presence of various salts (bicarbonate, sulfate, phosphate, and chloride). Characterization results revealed that electron transfer among NMS, NaClO, and organic contaminants was responsible for NaClO activation. Then NaClO-based Fenton-like process was proposed by tracing the degradation intermediates of methyl orange (MO) and generations of reactive oxygen species in the MO/NMS/NaClO system. This study presents the potential of NMS to activate NaClO and enhance ionic organic contaminants removal from aquatic environments.

11.
Environ Pollut ; 293: 118587, 2022 Jan 15.
Artigo em Inglês | MEDLINE | ID: mdl-34843845

RESUMO

Trace elements contamination in soil has aroused global concern nowadays, but the efficient, multifunctional, and economically viable method still remains a major challenge. In this research study, a sulfide Fe3O4 coated biochar composite (S/Fe-BC) has been synthesized successfully and applied to As(III)/Pb(II) co-contaminated soil. The immobilization efficiency of S/Fe-BC (2%) for the two elements exceeded 90%, and could ensure the synchronous and efficient immobilization in a wide range of pH (4.0-8.0). The TCLP-As and Pb amounts were sharply dropped after 28 days of stabilization; Meanwhile, a majority of exchangeable and carbonate-bound fractions of As and Pb were transferred into the less accessible residuals. Compared with Fe3O4 coated BC, the good immobilization performance of S/Fe-BC was mainly related to the enhancement of specific surface area, improvement of ionic exchange process, followed by the increase of Pb(II) precipitation and As(III) oxidation. Furthermore, competitive and synergistic effects were observed. In depth characterization analyses revealed the simultaneous immobilization mechanisms involving the adsorption, precipitation (Pb(OH)2, PbSO4, and PbS), co-precipitation (PbFeAsO4(OH)), and oxidation. Conclusively, outstanding performance of S/Fe-BC composite is considered as a good multifunctional potential candidate for the immobilization of trace elements from a soil system.


Assuntos
Poluentes do Solo , Solo , Carvão Vegetal , Poluentes do Solo/análise , Sulfetos
12.
RSC Adv ; 11(51): 32038-32046, 2021 Sep 27.
Artigo em Inglês | MEDLINE | ID: mdl-35495540

RESUMO

With the background of contemporary art, using comprehensive materials to create artworks is becoming more and more common. The new era of digital image-based copperplate artworks, using photosensitive lithography, has given traditional art forms new life and greater popularity in the digital age. However, the patterns and textures of the works created by the new techniques are generally shallow, and the copper surface is easily damaged and loses its aesthetic value, which makes it a practical problem to protect such works more effectively. In this paper, a facile method is adopted, wherein a superhydrophobic film is constructed on the surface of copperplate images by straightforward immersion in (heptadecafluoro-1,1,2,2-tetradecyl)trimethoxysilane (FAS-17) solution to achieve the anticorrosive protection of copperplate artworks. The hydrophobicity of the copper surface was analyzed using an instrument that measures contact angles. The superhydrophobic surface morphology and composition were analyzed with a scanning electron microscope coupled with an energy-dispersive spectrometer, and the corrosion resistance was analyzed using an electrochemical workstation. A systematic study is presented on the effect of the immersion time in FAS-17 and the concentration of FAS-17, and the optimal preparation conditions of the superhydrophobic film were determined, which means that the copper substrates were immersed in 0.7 mol L-1 FAS-17 for 40 min. After the treatment of the surface to make it superhydrophobic, the contact angle and the corrosion inhibition efficiency of the copperplate etching surface reached 161.2° and 95.7%, respectively. The results show that the superhydrophobic film was successfully prepared on the surface of the artwork based on copper, which can effectively improve the corrosion resistance and is beneficial for the long-term protection of artwork.

13.
Sci Total Environ ; 781: 146633, 2021 Aug 10.
Artigo em Inglês | MEDLINE | ID: mdl-33798875

RESUMO

Although flow-through electrode has demonstrated its potential in treating oily wastewater, few studies noted influence of oil droplet behavior on treating oil/water emulsions. In order to explore the influence of oil droplet behavior in a flow-through electrode cell on treating oil/water emulsions with low-salt concentrations, an electrochemical micromembrane cell was applied to treat oil/water emulsions with 0-0.8 g/L NaCl. High chemical oxygen demand (COD) reduction (80-90%) was obtained in treating Sodium dodecylbenzene sulfonate (SDBS) or Tween 80 emulsion by flow-through electrode, while the later had the higher permeate flux (900 mL/min around). The low salt concentration (0.5 g/L NaCl) achieved high COD reduction (87%) and good permeate flux (600 mL/min). Observations using optical microscopy revealed severe deformation of the shape of the charged oil droplet at the flow-through electrode interface. The wetting of oil droplets at the electrode interface occurred when the membrane acted as an anode, which resulted in flow-through electrode fouling, and subsequently, the reduction in permeate flux and treatment efficiency. The results of this study offer an attractive option when using flow-through electrode to treat oil-in-water emulsions under low-salinity conditions.

14.
J Hazard Mater ; 416: 125768, 2021 Aug 15.
Artigo em Inglês | MEDLINE | ID: mdl-33836323

RESUMO

Flow-through electrodes generally outcompete traditional parallel-plate electrodes in current efficiency and mass transfer. High-performance electrode materials can be costly and complicated to fabricate, hindering their wide application. In this study, we used commercial graphite felt (GF) as the cathode of a flow-through electrochemical cell to investigate its potential in treating Cr(VI) solution through electroreduction. The flow-through design with the porous GF electrode allowed sufficient contact surface with Cr(VI) and single-pass tests demonstrated a high reduction efficiency (95~100%) [117 mg/L~3 mg/L Cr(VI)] under acidic conditions. Slow flow rate and high current promoted electroreduction of Cr(VI). The presence of other metal ions could further improve Cr(VI) reduction at low flow rates due to enhanced conductivity in dilute solutions and generation of low valent ions as reducing agents. At fast flow rates, competition of these ions for reduction decreased Cr(VI) reduction efficiency. Moreover, an acidic environment prevented the coating of an insoluble layer on the GF surface and promoted durable performance, with a lower energy consumption [0.46 kWh for treating 100 L 117 mg/L Cr(VI) solution per unit area of GF]. This work demonstrated the potential of Cr(VI) detoxification using GF cathodes in flow-through electrochemical cell.

15.
RSC Adv ; 10(17): 9868-9877, 2020 Mar 06.
Artigo em Inglês | MEDLINE | ID: mdl-35498583

RESUMO

Electricity generation in microbial fuel cells can be restricted by a few factors, such as the effective area of the anode for biofilm attachment, diffusion limitation of substrates and internal resistance. In this paper, a suspended anode (carbon-based felt granule)-type microbial fuel cell was developed to make full use of the volume of the anode chamber and provide a larger surface area of the anode for the growth of exoelectrogenic bacteria. The current collector was rotated in the anodic chamber to contact with the suspended granules intermittently and achieve better mixing. The open-circuit voltage reached steady state at around 0.83 V. The maximum power density obtained from each scenario increased steadily with the increase in mixing rate. The internal resistance decreased when the rotational rate and the content of the carbon granules were increased. The maximum power density reached 951 ± 14 mW m-3 with a corresponding minimum internal resistance of 162.9 ± 3.5 Ω when the mass of carbon granules was 50 g and the rotational rate was 300 rpm. The suspended microbes made negligible contribution to the power density. The microbial fuel cell with a higher content of carbon granules had lower coulombic efficiency and lower relative abundance of exoelectrogenic bacteria.

16.
Water Environ Res ; 91(12): 1589-1599, 2019 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-31145823

RESUMO

The electrocatalytic activities of a series of copper alloys, Cu/Ni/Zn (Cu60 Ni15 Zn25 ) and Cu/Zn (Cu62 Zn38 ), toward the reduction of nitrate were investigated, in comparison with that of pure copper. Electrochemical analysis showed that the copper alloy electrode exhibited higher electrochemical reduction rate of nitrate. The extreme difference (R) between the orthogonal experiments revealed that the NO 3 - - N concentration was the main determinant of the removal percentage, followed by the current density and electrolyte concentration, while the impact of the initial pH was minimal. The conditions of the electrolysis experiments with Cu/Ni/Zn and Cu/Zn cathodes were optimized as follows: a current density of 8 mA/cm2 , a NaCl concentration of 2.0 g/L, and an initial pH of 3.0. The nitrate reduction reaction process with copper alloy cathodes was confirmed by electrochemical analysis and electrolysis experiments. Therefore, copper alloyed with Zn and Ni is a feasible option for practical application to the electrocatalytic reduction of nitrate. PRACTITIONER POINTS: Alloy of Cu, Zn, and Ni improved electrochemical nitrate reduction reaction. Electrochemical reduction of nitrate was confirmed in the presence of NaCl. The optimized current density with copper alloy cathodes was 6 mA/cm2 . A feasible strategy was provided for the improving nitrate removal and minimizing by-products.


Assuntos
Ligas , Cobre , Eletrodos , Nitratos , Óxidos de Nitrogênio
17.
Water Res ; 42(1-2): 1-12, 2008 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-17692889

RESUMO

Biogenic corrosion of sewers represents a cost of about 10% of total sewage treatment cost in Flanders (Belgium) and is further increasing. In the past, research has resulted in a number of prevention methods, such as injection of air, oxygen, H(2)O(2), NaClO, FeCl(3) and FeSO(4). The possibility of biological oxidation of sulfide using nitrate as the electron acceptor has also been explored in sewer systems. However, all of these methods have a problem with the high cost (euro 1.9-7.2 kg(-1)S removal). In this review, new approaches for hydrogen sulfide emission control in sewer systems are discussed. The control of hydrogen sulfide emission by using a microbial fuel cell (MFC) can be cost-effective while the BOD is removed partially. The use of phages that target sulfate-reducing bacteria (SRB) can possibly inhibit sulfide formation. Novel inhibitors, such as slow release solid-phase oxygen (MgO(2)/CaO(2)) and formaldehyde, warrant further study to control hydrogen sulfide emission in sewer systems.


Assuntos
Poluentes Atmosféricos , Poluição do Ar/prevenção & controle , Drenagem Sanitária , Sulfeto de Hidrogênio , Poluentes Atmosféricos/química , Poluentes Atmosféricos/metabolismo , Antibacterianos/farmacologia , Bactérias/efeitos dos fármacos , Bactérias/metabolismo , Bactérias/virologia , Bacteriófagos/fisiologia , Fontes Geradoras de Energia , Sulfeto de Hidrogênio/química , Sulfeto de Hidrogênio/metabolismo , Oxirredução
18.
Sci Total Environ ; 573: 1070-1078, 2016 Dec 15.
Artigo em Inglês | MEDLINE | ID: mdl-27611357

RESUMO

Natural magnetite and hematite were explored to decrease sulfide in sewage, compared with iron salts (FeCl3 and FeSO4). A particle size of magnetite and hematite ranging from 45 to 60µm was used. The results showed that 40mgL-1 of powdered magnetite and hematite addition decreased the sulfide in sewage by 79%and 70%, respectively. The achieved decrease of sulfide production capacities were 197.3, 210.6, 317.6 and 283.3mgSg-1Fe for magnetite, hematite, FeCl3 and FeSO4 at the optimal dosage of 40mgL-1, respectively. Magnetite and hematite provided a higher decrease of sulfide production since more iron ions are capable of being released from the solid phase, not because of adsorption capacity of per gram iron. Besides, the impact on pH and oxidation-reduction potential (ORP) of hematite addition was negligible; while magnetite addition resulted in slight increase of 0.3-0.5 on pH and 10-40mV on ORP. Powdered magnetite and hematite thus appear to be suitable for sulfide decrease in sewage, for their sparing solubility, sustained-release, long reactive time in sewage as well as cost-effectiveness, compared with iron salts. Further investigation over long time periods under practical conditions are needed to evaluate the possible settlement in sewers and unwanted (toxic) metal elements presenting as impurities. CAPSULE ABSTRACT: Powdered magnetite and hematite were more cost-effective at only 30% costs of iron salts, such as FeCl3 and FeSO4 for decreasing sulfide production in sewage.


Assuntos
Compostos Férricos/química , Óxido Ferroso-Férrico/química , Esgotos/química , Sulfetos/análise , Poluentes Químicos da Água/análise , Análise da Demanda Biológica de Oxigênio , Modelos Teóricos , Tamanho da Partícula , Pós , Solubilidade , Sulfetos/química , Poluentes Químicos da Água/química
19.
Res Microbiol ; 156(1): 88-92, 2005.
Artigo em Inglês | MEDLINE | ID: mdl-15636752

RESUMO

A bio-anode reactor and a bio-cathode reactor were developed to investigate the microenvironments around anodes and cathodes and their effects on denitrification. With an applied current of 40 mA, the oxidation-reduction potentials (ORPs) in the bio-cathode and bio-anode reactors were 100-200 mV lower and 50 mV higher, respectively, than that in the control reactor (a normal bio-reactor). The cathode reaction enhanced denitrification and the anode reaction inhibited denitrification. At 40 mA, the denitrification rate in the bio-cathode reactor was 55.1% higher than that in the control reactor. At 75 mA, the denitrification rate in the bio-anode reactor was just 33.5% of that in control reactor. Electric current of less than 20 mA had no effect on the most probable number (MPN) of denitrifiers, but at 75 mA, the MPN of denitrifiers decreased by 90% in the bio-anode reactor. In the bio-cathode reactor, the MPN of denitrifiers increased more than 100% for the lower ORP environment produced by a cathode reaction at 75 mA.


Assuntos
Bactérias/metabolismo , Reatores Biológicos , Eletrodos , Compostos de Nitrogênio/metabolismo , Eletroquímica , Eletrólise , Microbiologia da Água , Poluição Química da Água
20.
Waste Manag ; 23(8): 703-8, 2003.
Artigo em Inglês | MEDLINE | ID: mdl-14522188

RESUMO

Only 1-2 percent of discarded dry batteries are recovered in China. It is necessary to find an economic and environmentally friendly process to recycle dry batteries in this developing country. Bioleaching is one of the few techniques applicable for the recovery of the toxic metals from hazardous spent batteries. Its principle is the microbial production of sulphuric acid and simultaneous leaching of metals. In this study, a system consisting of a bioreactor, settling tank and leaching reactor was developed to leach metals from nickel-cadmium batteries. Indigenous thiobacilli, proliferated by using nutritive elements in sewage sludge and elemental sulphur as substrates, was employed in the bioreactor to produce sulphuric acid. The overflow from the bioreactor was conducted into the settling tank. The supernatant in the settling tank was conducted into the leaching reactor, which contained the anode and cathodic electrodes obtained from nickel-cadmium batteries. The results showed that this system was valid to leach metals from nickel-cadmium batteries, and that the sludge drained from the bottom of the settling tank could satisfy the requirements of environmental protection agencies regarding agricultural use.


Assuntos
Reatores Biológicos , Cádmio , Conservação de Recursos Energéticos , Fontes Geradoras de Energia , Níquel , Agricultura , Cádmio/análise , China , Níquel/análise , Eliminação de Resíduos/métodos , Ácidos Sulfúricos/química
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