RESUMO
Acyl radicals have been generated from the decarboxylation of α-oxocarboxylic acids by using a readily accessible organic pyrimidopteridine photoredox catalyst under ultraviolet-A (UV-A) light irradiation. These reactive acyl radicals were smoothly added to olefins such as styrenes and diverse Michael acceptors, with the assistance of H2O/D2O as hydrogen donors, enabling easy access to a diverse range of ketones/ß-deuterio ketones. A wide range of α-oxocarboxylic acids are compatible with this reaction, which shows a reliable, atom-economical, and eco-friendly protocol. Furthermore, postsynthetic diversifications and applications are presented.
RESUMO
Herein, a novel and facile organic photosensitizer (thioxanthone)-mediated energy-transfer-enabled (EnT-enabled) dearomative [2+2] cycloaddition of aromatic heterocycles/maleimides for green synthesis of cyclobutane-fused polycyclic skeletons is reported. Mechanistic investigations revealed that different EnT pathways by triplet thioxanthone were initiated when different aromatic heterocycles participated in the reaction, giving the corresponding excited intermediates, which underwent the subsequent intermolecular [2+2] cycloaddition to access the desired highly functionalized cyclobutane-fused polycyclic skeletons.
RESUMO
Ag/BiPbO2Cl nanosheet composites were successfully prepared by hydrothermal synthesis and photo-reduction. The morphology, microstructure, and optical properties of the as-prepared Ag/BiPbO2Cl nanosheet composites were characterized using TEM, XRD, and UV-Vis diffuse reflection spectroscopy. The prepared Ag/BiPbO2Cl nanosheet composites with 0.5 wt% Ag exhibit favorable photocatalytic activity, which is 3.6 times that of BiPbO2Cl nanosheet. The enhanced photocatalytic properties can be attributed to the inner electromagnetic field, higher visible light response range, excellent conductivity, and lower Fermi level of Ag.