What Exactly Can Bionic Strategies Achieve for Flexible Sensors?

Flexible sensors have attracted great attention in the field of wearable electronic devices due to their deformability, lightness, and versatility. However, property improvement remains a key challenge. Fortunately, natural organisms exhibit many unique response mechanisms to various stimuli, and the corresponding structures and compositions provide advanced design ideas for the development of flexible sensors. Therefore, this Review highlights recent advances in sensing performance and functional characteristics of flexible sensors from the perspective of bionics for the first time. First, the "twins" of bionics and flexible sensors are introduced. Second, the enhancements in electrical and mechanical performance through bionic strategies are summarized according to the prototypes of humans, plants, and animals. Third, the functional characteristics of bionic strategies for flexible sensors are discussed in detail, including self-healing, color-changing, tangential force, strain redistribution, and interfacial resistance. Finally, we summarize the challenges and development trends of bioinspired flexible sensors. This Review aims to deepen the understanding of bionic strategies and provide innovative ideas and references for the design and manufacture of next-generation flexible sensors.

Laser-Patterned Hierarchical Aligned Micro-/Nanowire Network for Highly Sensitive Multidimensional Strain Sensor.

Flexible multidirectional strain sensors capable of simultaneously detecting strain amplitudes and directions have attracted tremendous interest. Herein, we propose a flexible multidirectional strain sensor based on a newly designed single-layer hierarchical aligned micro-/nanowire (HAMN) network. The HAMN network is efficiently fabricated using a one-step femtosecond laser patterning technology based on a modulated line-shaped beam. The anisotropic performance is attributed to the significantly different morphological changes caused by an inhomogeneous strain redistribution among the HAMN network. The fabricated strain sensor exhibits high sensitivity (gauge factor of 65 under 2.5% strain and 462 under larger strains), low response/recovery time (140 and 322 ms), and good stability (over 1000 cycles). Moreover, this single-layer strain sensor with high selectivity (gauge factor differences of ∼73 between orthogonal strains) is capable of distinguishing multidimensional strains and exhibits decoupled responses under low strains (<1%). Therefore, the strain sensors enable the precise monitoring of subtle movements, including radial pulses and wrist bending, and the rectification of pen-holding posture. Benefitting from these remarkable performances, the HAMN-based strain sensors show potential applications, including healthcare and complex human motion monitoring.

Mechanocombinatorially Screening Sensitivity of Stretchable Strain Sensors.

Stretchable strain sensors have aroused great interest for their application in human activity recognition, health monitoring, and soft robotics. For various scenarios involving the application of different strain ranges, specific sensitivities need to be developed, due to a trade-off between sensor sensitivity and stretchability. Traditional stretchable strain sensors are developed based on conductive sensing materials and still lack the function of customizable sensitivity. A novel strategy of mechanocombinatorics is proposed to screen the sensor sensitivity based on mechanically heterogeneous substrates. Strain redistribution over substrates is optimized by mechanics and structure parameters, which gives rise to customizable sensitivity. As a proof of concept, a local illumination method is used to fabricate heterogeneous substrates with customizable mechanics and structure parameters. A library of mechanocombinatorial strain sensors is created for extracting the specific sensitivity. Thus, not only is an effective strategy for screening of sensor sensitivity demonstrated, but a contribution to the mechanocombinatorial strategy for personalized stretchable electronics is also made.

Surface Strain Redistribution on Structured Microfibers to Enhance Sensitivity of Fiber-Shaped Stretchable Strain Sensors.

Fiber-shaped stretchable strain sensors with small testing areas can be directly woven into textiles. This paves the way for the design of integrated wearable devices capable of obtaining real-time mechanical feedback for various applications. However, for a simple fiber that undergoes uniform strain distribution during deformation, it is still a big challenge to obtain high sensitivity. Herein, a new strategy, surface strain redistribution, is reported to significantly enhance the sensitivity of fiber-shaped stretchable strain sensors. A new method of transient thermal curing is used to achieve the large-scale fabrication of modified elastic microfibers with intrinsic microbeads. The proposed strategy is independent of the active materials utilized and can be universally applied for various active materials. The strategy used here will shift the vision of the sensitivity enhancement method from the active materials design to the mechanical design of the elastic substrate, and the proposed strategy can also be applied to nonfiber-shaped stretchable strain sensors.