Towards disentangling coupled electronic-vibrational dynamics in ultrafast non-adiabatic processes
Faraday Discuss
; (115): 33-48; discussion 79-102, 2000.
Article
em En
| MEDLINE
| ID: mdl-11040499
ABSTRACT
Femtosecond time-resolved photoelectron spectroscopy is emerging as a new technique for investigating polyatomic excited state dynamics. Due to the sensitivity of photoelectron spectroscopy to both electronic configurations and vibrational dynamics, it is well suited to the study of non-adiabatic processes such as internal conversion, which often occur on sub-picosecond time scales. We discuss the technical requirements for such experiments, including lasers systems, energy- and angle-resolved photoelectron spectrometers and new detectors for coincidence experiments. We present a few examples of these methods applied to problems in diatomic wavepacket dynamics and ultrafast non-adiabatic processes in polyatomic molecules.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Faraday Discuss
Assunto da revista:
QUIMICA
Ano de publicação:
2000
Tipo de documento:
Article
País de afiliação:
Canadá