Regio- and stereocontrol in rhenium-catalyzed transposition of allylic alcohols.
J Am Chem Soc
; 132(17): 5962-3, 2010 May 05.
Article
em En
| MEDLINE
| ID: mdl-20387811
ABSTRACT
A hydroxyl group-directed, highly regio- and stereoselective transposition of allylic alcohols based on rhenium catalysis has been developed. The method is suitable for a direct isomerization of acetals into the thermodynamically preferred isomer as long as one of the hydroxyl groups is allylic. This method will expand the scope of rhenium-catalyzed alcohol transpositions for complex molecule synthesis.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Rênio
/
Propanóis
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2010
Tipo de documento:
Article
País de afiliação:
Estados Unidos