Synthesis and optical resolution of inherently chiral difunctionalized tribenzotriquinacenes.
J Org Chem
; 75(19): 6704-7, 2010 Oct 01.
Article
em En
| MEDLINE
| ID: mdl-20804178
ABSTRACT
The synthesis of several inherently chiral tribenzotriquinacenes (TBTQs) bearing one single mono- or difunctionalized aromatic nucleus and the optical resolution of one of these derivatives, a TBTQ-based salicylic acid (11), are described for the first time. Efficient access to enantiopure, inherently chiral tribenzotriquinacenes may lay a foundation for studies of novel container compounds, supramolecular aggregation, chiral recognition, and asymmetric catalysis.
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01-internacional
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MEDLINE
Assunto principal:
Compostos Policíclicos
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Óptica e Fotônica
Idioma:
En
Revista:
J Org Chem
Ano de publicação:
2010
Tipo de documento:
Article