Rapid synthesis of radioactive transition-metal carbonyl complexes at ambient conditions.
Inorg Chem
; 51(12): 6431-3, 2012 Jun 18.
Article
em En
| MEDLINE
| ID: mdl-22663355
ABSTRACT
Carbonyl complexes of radioactive transition metals can be easily synthesized with high yields by stopping nuclear fission or fusion products in a gas volume containing CO. Here, we focus on Mo, W, and Os complexes. The reaction takes place at pressures of around 1 bar at room temperature, i.e., at conditions that are easy to accommodate. The formed complexes are highly volatile. They can thus be transported within a gas stream without major losses to setups for their further investigation or direct use. The rapid synthesis holds promise for radiochemical purposes and will be useful for studying, e.g., chemical properties of superheavy elements.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2012
Tipo de documento:
Article
País de afiliação:
Alemanha