Layered silicate as an excellent partner of a TiO2 photocatalyst for efficient and selective green fine-chemical synthesis.
J Am Chem Soc
; 135(32): 11784-6, 2013 Aug 14.
Article
em En
| MEDLINE
| ID: mdl-23902420
ABSTRACT
When the partial oxidation of benzene to phenol, which is one of the most important reactions in chemical industry, was conducted using TiO2 in the presence of a phenol-philic adsorbent derived from a layered silicate, phenol was recovered in unprecedentedly high yield and purity. This resulted from the fact that the adsorbent captured the generated phenol promptly, selectively, and effectively to prevent the overoxidation, after which the captured phenol could be easily eluted.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2013
Tipo de documento:
Article
País de afiliação:
Japão