Bis(µ2-benzoato-κ(2) O:O')bis-[(benzoato-κ(2) O,O')bis(4,4'-bi-pyridine-κN)cobalt(II)]-benzoic acid (1/6).
Acta Crystallogr Sect E Struct Rep Online
; 70(Pt 1): m21-2, 2014 Jan 01.
Article
em En
| MEDLINE
| ID: mdl-24526949
ABSTRACT
In the title compound, [Co2(C7H5O2)4(C10H8N2)4]·6C6H5COOH, the centrosymmetric cobalt dimer co-crystallizes with six mol-ecules of benzoic acid. Each Co(II) atom is coordinated by four O atoms in a distorted square-planar arrangement while the N atoms are located in apical positions. The dihedral angles between the rings comprising each of the 4,4'-bipyridyl ligands are 25.2â
(2) and 22.8â
(2)°. In the crystal, the three-dimensional network is assembled by O-Hâ¯O and C-Hâ¯O hydrogen bonds.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2014
Tipo de documento:
Article
País de afiliação:
México