Iron Carbide Nanoparticles Encapsulated in Mesoporous Fe-N-Doped Carbon Nanofibers for Efficient Electrocatalysis.
Angew Chem Int Ed Engl
; 54(28): 8179-83, 2015 Jul 06.
Article
em En
| MEDLINE
| ID: mdl-26014581
ABSTRACT
Exploring low-cost and high-performance nonprecious metal catalysts (NPMCs) for oxygen reduction reaction (ORR) in fuel cells and metal-air batteries is crucial for the commercialization of these energy conversion and storage devices. Here we report a novel NPMC consisting of Fe3 C nanoparticles encapsulated in mesoporous Fe-N-doped carbon nanofibers, which is synthesized by a cost-effective method using carbonaceous nanofibers, pyrrole, and FeCl3 as precursors. The electrocatalyst exhibits outstanding ORR activity (onset potential of -0.02â
V and half-wave potential of -0.140â
V) closely comparable to the state-of-the-art Pt/C catalyst in alkaline media, and good ORR activity in acidic media, which is among the highest reported activities of NPMCs.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2015
Tipo de documento:
Article