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Assemblies of ionic zinc chlorins assisted by water-soluble polypeptides.
Miyatake, Tomohiro; Hasunuma, Yuki; Mukai, Yumi; Oki, Hisato; Watanabe, Mikiya; Yamazaki, Shohei.
Afiliação
  • Miyatake T; Department of Materials Chemistry, Ryukoku University, Otsu, Shiga 520-2194, Japan; Innovative Materials and Processing Research Center, Ryukoku University, Otsu, Shiga 520-2194, Japan. Electronic address: miyatake@rins.ryukoku.ac.jp.
  • Hasunuma Y; Department of Materials Chemistry, Ryukoku University, Otsu, Shiga 520-2194, Japan.
  • Mukai Y; Department of Materials Chemistry, Ryukoku University, Otsu, Shiga 520-2194, Japan.
  • Oki H; Department of Materials Chemistry, Ryukoku University, Otsu, Shiga 520-2194, Japan.
  • Watanabe M; Department of Materials Chemistry, Ryukoku University, Otsu, Shiga 520-2194, Japan.
  • Yamazaki S; Department of Materials Chemistry, Ryukoku University, Otsu, Shiga 520-2194, Japan.
Bioorg Med Chem ; 24(5): 1155-61, 2016 Mar 01.
Article em En | MEDLINE | ID: mdl-26852341
Artificial chlorophyll-peptide complexes were prepared by mixing ionic chlorophyll derivatives and oligopeptides in aqueous media containing a small amount of organic solvent. The pigment-peptide complexes provided chlorophyll assemblies showing a sharp red-shifted Qy absorption band concomitant with giant circular dichroism signals. The polypeptide-assisted assemblies of chlorophyllous pigments would afford a good model for photosynthetic apparatuses such as pigment-protein complexes of light-harvesting antennas.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Peptídeos / Clorofila / Metaloporfirinas Idioma: En Revista: Bioorg Med Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2016 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Peptídeos / Clorofila / Metaloporfirinas Idioma: En Revista: Bioorg Med Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2016 Tipo de documento: Article