Re(CO)3-Templated Formation of Aza(dibenzo)dipyrromethenes.
Inorg Chem
; 55(7): 3209-11, 2016 Apr 04.
Article
em En
| MEDLINE
| ID: mdl-26998738
The Re(CO)3 unit was used to template the formation of aza(dibenzopyrro)methene (ADBM) in the presence of pyridine or N-methylimidazole. The products of these template reactions are six-coordinate complexes, with a facial arrangement of the carbonyls, a bidentate ADBM, and a sixth ligand (pyridine or N-methylimiadozle). Three types of ADBM ligands are produced from these reactions, depending on the degree of hydrolysis; bis(imine)-terminated, bis(oxo)-terminated, and mixed-imine/oxo chelates were formed.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2016
Tipo de documento:
Article
País de afiliação:
Estados Unidos