Selection of two optional covalent bonds by electric stimuli: dual catalytic switching of redox-active copper.

Kamamoto, Yu; Nitta, Yuya; Kubo, Kazuyuki; Mizuta, Tsutomu; Kume, Shoko

Kamamoto, Yu; Nitta, Yuya; Kubo, Kazuyuki; Mizuta, Tsutomu; Kume, Shoko.

Afiliação

Kamamoto Y; Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan. skume@hiroshima-u.ac.jp.
Nitta Y; Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan. skume@hiroshima-u.ac.jp.
Kubo K; Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan. skume@hiroshima-u.ac.jp.
Mizuta T; Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan. skume@hiroshima-u.ac.jp.
Kume S; Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan. skume@hiroshima-u.ac.jp.

Chem Commun (Camb) ; 52(69): 10486-9, 2016 Aug 18.

Article em En | MEDLINE | ID: mdl-27435917

ABSTRACT

ABSTRACT

Two types of redox functionality were selected for covalent immobilization on a carbon electrode, using an electric potential as the sole stimulus. A redox-active copper catalyst transformed a terminal alkyne in two ways with and without an oxidation process, to form a triazole or butadiyne.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2016 Tipo de documento: Article País de afiliação: Japão

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