Electrochemical hydrogenation of a benzannulated pyridine to a dihydropyridine in acidic solution.
Chem Commun (Camb)
; 54(4): 338-341, 2018 Jan 04.
Article
em En
| MEDLINE
| ID: mdl-29218347
ABSTRACT
The electrochemistry of pyridines in acidic solution is dominated by a 'weak acid' reduction on the cyclic voltammetry timescale. Here we show that electrochemical hydrogenation of a benzannulated pyridine, phenanthridine (1), to the biomimetic hydride donor 1,2-dihydrophenanthridine (1-H2) can occur selectively at glassy carbon electrodes over longer timescales of potentiostatic electrolysis.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
Canadá