Iron-Catalyzed Decarboxylative Olefination of Cycloketone Oxime Esters with α,ß-Unsaturated Carboxylic Acids via C-C Bond Cleavage.
Org Lett
; 20(15): 4614-4617, 2018 08 03.
Article
em En
| MEDLINE
| ID: mdl-30024173
ABSTRACT
An iron-catalyzed redox-neutral, decarboxylative olefination of cycloketone oxime esters with α,ß-unsaturated carboxylic acids has been developed. This reaction involves an iminyl radical mediated C-C bond cleavage/radical addition/decarboxylation cascade. This protocol is highlighted by its low-cost catalytic system and readily accessible starting materials, as well as broad substrate scope, thus providing facile access to structurally diverse cyano-containing alkenes.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Org Lett
Assunto da revista:
BIOQUIMICA
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
China