East Siberian Arctic background and black carbon polluted aerosols at HMO Tiksi.

ABSTRACT

Assessment of Arctic pollution is hampered by a lack of aerosol studies in Northern Siberia. Black carbon observations were carried out at the Hydrometeorological Observatory Tiksi, a coast of Laptev sea, from September 2014 to September 2016. Aerosol sampling was accompanied by physico-chemical characterization. BC climatology showed a seasonal variation with highest concentrations from January to March (up to 450ng/m3) and lowest ones for June and September (about 20ng/m3). Stagnant weather and stable atmosphere stratification resulted in accumulation of pollution, in dependence on the wind direction and air mass transportation. Carbon fractions, functionalities, ions, and elements are associated to marine, biogenic, and continental sources. In September low OC, aliphatic, carbonyls, amines, and hydroxyls characterize background aerosols. Na+/Cl- ratio much higher than in sea-salt indicates a strong Cl depletion. Increased OC, aromatic, carbonyls, and nitrocompounds as well as waste burning markers K+, Cl-, and PO42- confirm impacts from Tiksi landfill burns. BC pollution episodes are differentiated through increased EBC and sulfates, related to gas flaring, industrial and residential emissions transported from Western Siberia while the increase of carbonyls, hydroxyl, and aromatic indicate emissions sources from Yakutia and Tiksi urban area. Arctic Haze aerosols are characterized by increased concentrations of SO42- in comparison with OC, much higher abundance of oxygenated compounds with respect to alkanes of anthropogenic origin. In summer rich organic chemistry indicates impacts of biogenic, local urban, and shipping sources as well as secondary aerosol formation influenced by emissions from low latitude Siberia.