Titanite-Containing Mineral Compositions and Their Chemical Treatment with Preparation of Functional Materials.

The waste of apatite-nepheline ore processing was chosen as the material of study for the present investigation. The chemical and phase compositions have been analyzed and the route of the new technology has been developed. Treatment of the waste with diluted hydrochloric acid enables to separate apatite, nepheline, titano-magnetite minerals from titanite (CaSiTiO5). The obtained titanite concentrate contains 30-32% of titanium dioxide. Interaction of titanite with hydrochloric acid under heating and stirring conditions results in calcium leaching. The titanite decomposition is accompanied by titanium and silica oxides precipitation. The resulting solid has been used as a precursor for the synthesis of functional materials. Mechanochemical activation of the precursor provides the structural and morphological disorder of the initial particles. Thermodynamic stability of activated particles is achieved by chemisorption or roasting.