Carbon nanotube spiderweb promoted growth of hierarchical transition metal dichalcogenide nanostructures for seamless devices.
Nanotechnology
; 31(36): 365601, 2020 Sep 04.
Article
em En
| MEDLINE
| ID: mdl-32428881
ABSTRACT
Hierarchical transition metal dichalcogenide (h-TMDC) nanostructures with abundant active edge sites and good electrical conductivity hold great promise for numerous applications. Here, we report a general method for the chemical synthesis of a series of large-area, free-standing h-TMDC films and their devices by using carbon nanotube (CNT) spiderwebs as both growth promoters and electrical/mechanical reinforcement networks. Our approach allows the seamless integration of h-TMDC nanostructures with abundant active edge sites and CNT networks with good electrical conductivity and mechanical flexibility. As a proof of concept, h-MoSe2/CNT hybrid films with CNT contacts have been chemically synthesized and applied as flexible electrocatalytic devices for hydrogen evolution reaction (HER). Owing to the seamless connection between the CNT contacts and the electroactive h-TMDC/CNT nanostructures, the flexible electrocatalytic devices exhibited excellent mechanical stability and maintained stable electrocatalytic performance under cyclic bendings. Our method can be readily extended to the large-scale production of various h-TMDC/CNT hybrid films and their seamless devices.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Nanotechnology
Ano de publicação:
2020
Tipo de documento:
Article