Fabrication and characterization of electrospun zein/nylon-6 (ZN6) nanofiber membrane for hexavalent chromium removal.

ABSTRACT

Zein has drawn attention for its great potential for biodegradability and adsorption of hexavalent chromium Cr(VI) that is a carcinogenic industrial pollutant. Zein is a biopolymer extracted from corn and is used for many purposes, but because of its poor stability in aqueous solution, a novel composite of zein and nylon-6 was used to synthesize a nanofibrous membrane using electrospinning to improve its stability and tensile strength. The scanning electron microscope (SEM) image of the zein/nylon-6 (ZN6) nanofiber membrane showed a smooth, beadless, and continuous structure of the nanofibers, but the Fourier transform infrared (FTIR) spectrum of pristine and Cr(VI) saturated ZN6 showed that peaks of secondary amide, carbonyl, and hydroxyl functional groups were involved in adsorption. Optimized experimental parameters were obtained with pH 2.0, contact time 60 min, adsorbent dosage 25 mg, and adsorbate concentration 5.0 mg Cr-VI/mL. Experimental results show that the ZN6 nanofibers removed 87% Cr(VI) with an adsorption capacity of 4.73 mg/g at ambient temperature. Also, the Langmuir isotherm fits well, and the adsorption process followed a pseudo-2nd-order kinetics with r2 of 0.90 and 0.99 respectively.