Space-Confined Guest Synthesis to Fabricate Sn-Monodispersed N-Doped Mesoporous Host toward Anode-Free Na Batteries.
Adv Mater
; 35(32): e2301967, 2023 Aug.
Article
em En
| MEDLINE
| ID: mdl-37167932
ABSTRACT
Severe issues including volume change and dendrite growth on sodium metal anodes hinder the pursuit of applicable high-energy-density sodium metal batteries. Herein, an in situ reaction approach is developed that takes metal-organic frameworks as nano-reactor and pore-former to produce a mesoporous host comprised of nitrogen-doped carbon fibers embedded with monodispersed Sn clusters (SnNCNFs). The hybrid host shows outstanding sodiophilicity that enables rapid Na infusion and ultralow Na nucleation overpotential of 2 mV. Its porous structure holds a high Na content and guides uniform Na deposition. Such host provides favorable Na plating/stripping with an average Coulombic efficiency of 99.96% over 2000 cycles (at 3 mA cm-2 and 3 mA h cm-2 ). The Na-infused SnNCNF anode delivers extreme Na utilization of 86% in symmetric cells (at 10 mA cm-2 and 10 mA h cm-2 ), outstanding rate capability and cycle life in Na-SnNCNF||Na3 V2 (PO4 )3 full cells (at 1 A g-1 for over 1000 cycles with capacity retention of 92.1%). Furthermore, high-energy/power-density anode-less and anode-free Na cells are achieved. This work presents an effective heteroatom-doping approach for fabricating multifunctional porous carbon materials and developing high-performance metal batteries.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Adv Mater
Assunto da revista:
BIOFISICA
/
QUIMICA
Ano de publicação:
2023
Tipo de documento:
Article