Exploring sulfur donor atom coordination chemistry with La(II), Nd(II), and Tm(II) using a terphenylthiolate ligand.

Gilbert-Bass, Kito; Stennett, Cary R; Grotjahn, Robin; Ziller, Joseph W; Furche, Filipp; Evans, William J

Gilbert-Bass, Kito; Stennett, Cary R; Grotjahn, Robin; Ziller, Joseph W; Furche, Filipp; Evans, William J.

Afiliação

Gilbert-Bass K; Department of Chemistry, University of California, Irvine, California 92697, USA. wevans@uci.edu.
Stennett CR; Department of Chemistry, University of California, Irvine, California 92697, USA. wevans@uci.edu.
Grotjahn R; Department of Chemistry, University of California, Irvine, California 92697, USA. wevans@uci.edu.
Ziller JW; Department of Chemistry, University of California, Irvine, California 92697, USA. wevans@uci.edu.
Furche F; Department of Chemistry, University of California, Irvine, California 92697, USA. wevans@uci.edu.
Evans WJ; Department of Chemistry, University of California, Irvine, California 92697, USA. wevans@uci.edu.

Chem Commun (Camb) ; 60(34): 4601-4604, 2024 Apr 23.

Article em En | MEDLINE | ID: mdl-38586900

ABSTRACT

ABSTRACT

To expand the range of donor atoms known to stabilize 4fn5d1 Ln(II) rare-earth metal (Ln) ions beyond the C, N, and O first row main group donor atoms, the Ln(III) sulfur donor terphenylthiolate iodide complexes, LnIII(SAriPr6)2I (AriPr6 = C6H3-2,6-(C6H2-2,4,6-iPr3)2, Ln = La, Nd) were reduced to form LnII(SAriPr6)2 complexes. These Ln(II) species were structurally characterized, analyzed by density functional theory (DFT) calculations, and compared to Tm(SAriPr6)2, which was synthesized from TmI2(DME)3.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Estados Unidos

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