Synthesis and reactivity of N-heterocyclic carbene (NHC) gold-fluoroalkoxide complexes.

Arnaut, Pierre; Bracho Pozsoni, Nestor; Nahra, Fady; Tzouras, Nikolaos V; Nolan, Steven P

Arnaut, Pierre; Bracho Pozsoni, Nestor; Nahra, Fady; Tzouras, Nikolaos V; Nolan, Steven P.

Afiliação

Arnaut P; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000 Ghent, Belgium. nikolaos.tzouras@ugent.be.
Bracho Pozsoni N; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000 Ghent, Belgium. nikolaos.tzouras@ugent.be.
Nahra F; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000 Ghent, Belgium. nikolaos.tzouras@ugent.be.
Tzouras NV; Materials & Chemistry (MATCH) unit, VITO (Flemish Institute for Technological Research), Boeretang 200, 2400 Mol, Belgium.
Nolan SP; Department of Chemistry and Centre for Sustainable Chemistry, Ghent University, Krijgslaan 281, S-3, 9000 Ghent, Belgium. nikolaos.tzouras@ugent.be.

Dalton Trans ; 53(28): 11952-11958, 2024 Jul 16.

Article em En | MEDLINE | ID: mdl-38958393

ABSTRACT

ABSTRACT

We disclose a novel series of N-heterocyclic carbene (NHC) gold complexes with varied steric and electronic properties, bearing fluorinated alkoxide anions. Early reactivity studies involving these synthons, lead to the synthesis of various complexes of relevance to gold chemistry and catalysis.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Dalton Trans Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Bélgica

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