Structural studies of 4-O-acetyl-alpha-N-acetylneuraminyl-(2 goes to 3)-lactose, the main oligosaccharide in echidna milk.
Carbohydr Res
; 100: 331-40, 1982 Mar 01.
Article
em En
| MEDLINE
| ID: mdl-7083254
ABSTRACT
The main oligosaccharide (50%) in the milk of the Australian echidna (Tachyglossus aculeatus) has been identified unequivocally as 4-O-acetyl-alpha-N-acetylneuraminyl-(2 goes to 3)-lactose. The 4-O-acetyl substituent of the sialic acid residue was characterized by g.l.c.-m.s. of the isolated (after mild, acid hydrolysis) and trimethyl-silylated/esterified sialic acid, and by m.s. (after derivatisation) and 500-MHz, 1H-n.m.r. spectroscopy of the intact oligosaccharide. Information about the glycosidic bonds was obtained by methylation analysis and 500-MHz, 1H-n.m.r. spectroscopy. This animals species is the third one known to produce 4-O-acetylated sialic acid.
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Base de dados:
MEDLINE
Assunto principal:
Oligossacarídeos
/
Leite
/
Tachyglossidae
/
Lactose
/
Monotremados
Limite:
Animals
Idioma:
En
Revista:
Carbohydr Res
Ano de publicação:
1982
Tipo de documento:
Article