Polarity reversal for enhanced in-situ electrochemical synthesis of H2O2 over banana-peel derived biochar cathode for water remediation.

The fabrication of a cost-efficient cathode is critical for in-situ electrochemical generation of hydrogen peroxide (H2O2) to remove persistent organic pollutants from groundwater. Herein, we tested a stainless-steel (SS) mesh wrapped banana-peel derived biochar (BB) cathode for in-situ H2O2 electrogeneration to degrade bromophenol blue (BPB) and Congo red (CR) dyes. Furthermore, polarity reversal is evaluated for the activation of BB surface via introduction of various oxygen containing functionalities that serve as active sites for the oxygen reduction reaction (ORR) to generate H2O2. Various parameters including the BB mass, current, as well as the solution pH have been optimized to evaluate the cathode performance for efficient H2O2 generation. The results reveal formation of up to 9.4 mg/L H2O2 using 2.0 g BB and 100 mA current in neutral pH with no external oxygen supply with a manganese doped tin oxide deposited nickel foam (Mn-SnO2@NF) anode to facilitate the oxygen evolution reaction (OER). This iron-free electrofenton (EF) like process enabled by the SSBB cathode facilitates efficient degradation of BPB and CR dyes with 87.44 and 83.63% removal efficiency, respectively after 60 min. A prolonged stability test over 10 cycles demonstrates the effectiveness of polarity reversal toward continued removal efficiency as an added advantage. Moreover, Mn-SnO2@NF anode used for the OER was also replaced with stainless steel (SS) mesh anode to investigate the effect of oxygen evolution on H2O2 generation. Although Mn-SnO2@NF anode exhibits better oxygen evolution potential with reduced Tafel slope, SS mesh anode is discussed to be more cost-efficient for further studies.

Flowery ln2MnSe4 Novel Electrocatalyst Developed via Anion Exchange Strategy for Efficient Water Splitting.

Oxygen and hydrogen generated by water electrolysis may be utilized as a clean chemical fuel with high gravimetric energy density and energy conversion efficiency. The hydrogen fuel will be the alternative to traditional fossil fuels in the future, which are near to exhaustion and cause pollution. In the present study, flowery-shaped In2MnSe4 nanoelectrocatalyst is fabricated by anion exchange reaction directly grown on nickel foam (NF) in 1.0 M KOH medium for oxygen evolution reaction (OER). The physiochemical and electrical characterization techniques are used to investigate the chemical structure, morphology, and electrical properties of the In2MnSe4 material. The electrochemical result indicates that synthesized material exhibits a smaller value of Tafel slope (86 mV/dec), lower overpotential (259 mV), and high stability for 37 h with small deterioration in the current density for a long time. Hence, the fabricated material responds with an extraordinary performance for the OER process and for many other applications in the future.