Unlocking superior performance of broadband powerful mid-IR optical parametric amplifiers with a BaGa2GeS6 crystal pumped at 1.24†µm.

We report on the development of a tunable (1.5-6.5 µm) femtosecond optical parametric amplifier (OPA) based on a novel, to the best of our knowledge, BaGa2GeS6 (BGGS) crystal with a Cr:Forsterite pumping laser. Total conversion efficiency as high as 28% is achieved in a robust two-stage setup resulting in the generation of a 340-µJ 1.67-µm signal and 100-µJ 4.65-µm idler pulses. A 5-optical-cycles 94-fs 6-µm idler pulses are demonstrated with a propriate dispersion compensation by Ge and GaAs plates. An experimental estimate is given for the effective nonlinearity of a BGGS material, which for our nonlinear process reaches 19.5 pm/V for Type II phase matching. The crystal is additionally tested as a final amplifier in a high-energy OPA, where total output reaches 1.2 mJ with more than 40% conversion efficiency. The demonstrated high nonlinearity, high damage threshold, and chemical stability of the polished surface make BGGS crystal an ideal candidate for the development of high-energy OPAs with multi-millijoule pumping lasers.

Frequency conversion of mid-IR lasers into the long-wavelength domain of 12-20 µm with AgGaSe2, BaGa2GeSe6 and PbIn6Te10 nonlinear crystals.

Difference frequency generation under mixing of repetitively-pulsed CO- and CO2-laser radiation in AgGaSe2, BaGa2GeSe6 and PbIn6Te10 nonlinear crystals was studied. Efficiency and refractive indices were examined for this frequency conversion into the long-wave domain of ∼12-20 µm in the mid-IR. The highest frequency conversion efficiency of 10-4 was obtained for a relatively new PbIn6Te10 crystal, which is an order of magnitude higher than previous results.

Sum frequency generation of multi-line slab radio frequency discharge carbon monoxide laser system with intracavity nonlinear BaGa2GeSe6 crystal.

A compact repetitively pulsed broadband carbon monoxide (CO) laser system with intracavity frequency conversion, for which a nonlinear crystal was also used as an output coupler, was launched for the first time, to the best of our knowledge. The laser system simultaneously operated in two spectral ranges: CO laser fundamental band (4.9-6.0 µm) and its sum frequencies band (2.45-2.95 µm). Different designs of the laser cavity were considered. Peak powers of the fundamental and sum frequencies laser pulses were up to 2 kW and 10 W, respectively.