RESUMEN
Metallic nanoparticles (NPs) play a significant role in nanocatalytic systems, which are important for clean energy conversion, storage, and utilization. Laser fabrication of metallic NPs relying on light-matter interactions provides many opportunities. It is essential to study the atomic structure transformation of nonactive monocrystalline metallic NPs for practical applications. The high-density stacking faults were fabricated in monocrystalline Au NPs through tuning the ultrafast laser-induced relaxation dynamics, and the thermal and dynamic stress effects on the atomic structure transformation were revealed. The atomic structure transformation mainly arises from the thermal effect, and the dynamic stress distribution induced by local energy deposition gives rise to the generation of stacking faults. Au NPs with abundant stacking faults show enhanced surface activity owing to their low coordination number. We suggest that this work expands the knowledge of laser-metallic nanomaterial interactions and provides a method for designing metallic NPs for a wide range of applications.