Preparation of novel Ti-based MnOx electrodes by spraying method for electrochemical oxidation of Acid Red B.

At different calcination conditions, titanium-based manganese oxides (MnOx) electrodes were fabricated by spraying method without adhesive. The MnOx/Ti electrodes were applied in electrochemical oxidation of wastewater treatment for the first time. The surface morphologies of electrodes were tested by scanning electron microscopy. The formation of different manganese oxidation states on electrodes was confirmed by X-ray diffraction and X-ray photoelectron spectroscopy. The electrochemical properties of the electrodes have been performed by means of cyclic voltammetry and electrochemical impedance spectroscopy. The characterizations revealed that the MnOx/Ti-350(20) electrode, prepared at calcination temperature of 350 °C for 20 min, exhibited fewer cracks on the electrode surface, larger electrochemically effective surface area and lower charge transfer resistance than electrodes prepared at other calcination conditions. Moreover, Acid Red B was used as target pollutant to test the electrode activity via monitoring the concentration changes by UV spectrophotometer. The results showed that the MnOx/Ti-350(20) electrode presented the best performance on decolorization of Acid Red B with the lowest cell potential during the process of electrochemical oxidation, and the chemical oxygen demand (COD) conversion was 50.7%. Furthermore, the changes of Acid Red B during the electrochemical oxidation process were proposed by the UV-vis spectra.

Effect of ultrasound on the dissolution of magnesium hydroxide: pH-stat and nanoscale observation.

It has been previously confirmed that the dissolution of magnesium hydroxide was a crucial procedure in its application process. Note that the ultrasound is an effective method for enhancing solid dissolution. In this study, the enhancement of ultrasound on the dissolution of magnesium hydroxide was investigated by the pH-stat method. The titrating results indicated that the promotion effect of ultrasound was only be observed at some certain cases, such as lower pH value. Meanwhile, the activation energy data obtained based on Shrinking Core Model for sonication case ranged from 6.56 to 49.13 kJ/mol, implying that magnesium hydroxide dissolution proceeds at sonication case cannot be explained well by this model. Nanoscale observation was conducted to identify the crystal surface variations during the dissolution process by using SEM and AFM. The analysis results indicated that the dissolution behaviors of magnesium hydroxide in the absence and presence of ultrasound were quite different. In the silent case, the dissolution followed the famous Stepwave model. As for the sonication case, the larger particle was broken into flake by the ultrasound firstly. Then, the heterogeneous global dissolution accompanied by the Stepwave model drove the dissolution process. The analysis results of nanoscale observation provided a reasonable explain for the kinetics research results on micro-level.