1.
J Am Chem Soc
; 137(14): 4678-80, 2015 Apr 15.
Artículo
en Inglés
| MEDLINE
| ID: mdl-25821991
RESUMEN
Acidities are commonly measured in polar solvents but catalytic reactions are typically carried out in nonpolar media. IR spectra of a series of phenols in CCl4 and 1% CD3CN/CCl4 provide relative acidities. Nonprotonated charged substituents with an appropriate counterion are found to enhance their Brønsted acidities and improve catalyst performance by orders of magnitude.