A 4D-Printable Photocurable Resin Derived from Waste Cooking Oil with Enhanced Tensile Strength.

In pursuit of enhancing the mechanical properties, especially the tensile strength, of 4D-printable consumables derived from waste cooking oil (WCO), we initiated the production of acrylate-modified WCO, which encompasses epoxy waste oil methacrylate (EWOMA) and epoxy waste oil acrylate (EWOA). Subsequently, a series of WCO-based 4D-printable photocurable resins were obtained by introducing a suitable diacrylate molecule as the second monomer, coupled with a composite photoinitiator system comprising Irgacure 819 and p-dimethylaminobenzaldehyde (DMAB). These materials were amenable to molding using an LCD light-curing 3D printer. Our findings underscored the pivotal role of triethylene glycol dimethacrylate (TEGDMA) among the array of diacrylate molecules in enhancing the mechanical properties of WCO-based 4D-printable resins. Notably, the 4D-printable material, composed of EWOA and TEGDMA in an equal mass ratio, exhibited nice mechanical strength comparable to that of mainstream petroleum-based 4D-printable materials, boasting a tensile strength of 9.17 MPa and an elongation at break of 15.39%. These figures significantly outperformed the mechanical characteristics of pure EWOA or TEGDMA resins. Furthermore, the EWOA-TEGDMA resin demonstrated impressive thermally induced shape memory performance, enabling deformation and recovery at room temperature and retaining its shape at -60 °C. This resin also demonstrated favorable biodegradability, with an 8.34% weight loss after 45 days of soil degradation. As a result, this 4D-printable photocurable resin derived from WCO holds immense potential for the creation of a wide spectrum of high-performance intelligent devices, brackets, mold, folding structures, and personalized products.

Cane Molasses Derived N-Doped Graphene Quantum Dots: Dynamic Quenching Synergistically Photoinduced Electron Transfer for the Instant Detection of Nitrofuran Antibiotics.

The development of a highly selective, simple, and rapid detection method for nitrofuran antibiotics (NFs) is of great significance for food safety, environmental protection, and human health. To meet these needs, in this work, cyan-color highly fluorescent N-doped graphene quantum dots (N-GQDs) were synthesized using cane molasses as the carbon source and ethylenediamine as the nitrogen source. The synthesized N-GQDs have an average particle size of 6 nm, a high fluorescence intensity with 9 times that of undoped GQDs, and a high quantum yield (24.4%) which is more than 6 times that of GQDs (3.9%). A fluorescence sensor based on N-GQDs for the detection of NFs was established. The sensor shows advantages of fast detection, high selectivity, and sensitivity. The limit of detection for furazolidone (FRZ) was 0.29 µM, the limit of quantification (LOQ) was 0.97 µM, and the detection range was 5-130 µM. The fluorescence quenching mechanism of the sensor was explored by fluorescence spectroscopy, UV-vis absorption spectroscopy, Stern-Volmer quenching constant, Zeta potential, UV-vis diffuse reflectance spectroscopy, and cyclic voltammetry. A fluorescence quenching mechanism of dynamic quenching synergized with photoinduced electron transfer was revealed. The developed sensor was also successfully applied for detecting FRZ in various real samples, and the results were satisfactory.

Detection of Microplastics Based on a Liquid-Solid Triboelectric Nanogenerator and a Deep Learning Method.

Microplastics are sub-millimeter-sized fragments of plastics, which have been found in environments to a great extent. They are relatively new pollutants that are difficult to be degraded. They not only cause irreversible adverse effects on microorganisms, animals, and plants but also enter the human body through the food chain and affect human health. However, due to their small size, variety, and differences in physical and chemical properties of microplastics, traditional detection and identification still face challenges. This work provides a method for detecting and classifying microplastics in liquids using a liquid-solid triboelectric nanogenerator (LS-TENG) in combination with a deep learning model. The experiment showed that the type and content of microplastics in the liquid had a great effect on the contact electrification between the liquid and the perfluoroethylene-propylene copolymer. After adding polyethylene, polypropylene, polyvinyl chloride, polyethylene terephthalate, and polystyrene microplastics to the liquids, it was found that the type and content of different microplastics have a significant impact on the output voltage signal of the LS-TENG sensor. When the mass fraction of microplastics ranged from 0.025 to 0.25 wt %, the voltage output of the LS-TENG sensor had a linear relationship with the mass fraction of microplastics. Therefore, a method for quantitatively detecting the content of microplastics using the LS-TENG sensor has been established. Based on the LS-TENG output voltage signal, a convolutional neural network deep learning model was used to identify different types of labels, and high recognition accuracy was achieved. These are of great significance for expanding the application prospect of LS-TENG and realizing the detection of microplastics in liquids.

Magnetic Carbon Quantum Dots/Iron Oxide Composite Based on Waste Rice Noodle and Iron Oxide Scale: Preparation and Photocatalytic Capability.

To provide an economical magnetic photocatalyst and introduce an innovative approach for efficiently utilizing discarded waste rice noodle (WRN) and iron oxide scale (IOS), we initially converted WRN into carbon quantum dots (CQDs) using a hydrothermal method, simultaneously calcining IOS to obtain iron oxide (FeOx). Subsequently, we successfully synthesized a cost-effective, magnetic CQDs/FeOx photocatalytic composite for the first time by combining the resulting CQDs and FeOx. Our findings demonstrated that calcining IOS in an air atmosphere enhanced the content of photocatalytically active α-Fe2O3, while incorporating WRN-based CQDs into FeOx improved the electron-hole pair separation, resulting in increased O2 reduction and H2O oxidation. Under optimized conditions (IOS calcination temperature: 300 °C; carbon loading: 11 wt%), the CQDs/FeOx composite, utilizing WRN and IOS as its foundation, exhibited exceptional and reusable capabilities in photodegrading methylene blue and tetracycline. Remarkably, for methylene blue, it achieved an impressive degradation rate of 99.30% within 480 min, accompanied by a high degradation rate constant of 5.26 × 10-3 min-1. This composite demonstrated reusability potential for up to ten photocatalytic cycles without a significant reduction in the degradation efficiency, surpassing the performance of IOS and FeOx without CQDs. Notably, the composite exhibited strong magnetism with a saturation magnetization strength of 34.7 emu/g, which enables efficient and convenient recovery in photocatalytic applications. This characteristic is highly advantageous for the large-scale industrial utilization of photocatalytic water purification.

A Meta-Analysis of Influencing Factors on the Activity of BiVO4-Based Photocatalysts.

With the continuous advancement of global industrialization, a large amount of organic and inorganic pollutants have been discharged into the environment, which is essential for human survival. Consequently, the issue of water environment pollution has become increasingly severe. Photocatalytic technology is widely used to degrade water pollutants due to its strong oxidizing performance and non-polluting characteristics, and BiVO4-based photocatalysts are one of the ideal raw materials for photocatalytic reactions. However, a comprehensive global analysis of the factors influencing the photocatalytic performance of BiVO4-based photocatalysts is currently lacking. Here, we performed a meta-analysis to investigate the differences in specific surface area, kinetic constants, and the pollutant degradation performance of BiVO4-based photocatalysts under different preparation and degradation conditions. It was found that under the loading condition, all the performances of the photocatalysts can be attributed to the single BiVO4 photocatalyst. Moreover, loading could lead to an increase in the specific surface area of the material, thereby providing more adsorption sites for photocatalysis and ultimately enhancing the photocatalytic performance. Overall, the construct heterojunction and loaded nanomaterials exhibit a superior performance for BiVO4-based photocatalysts with 136.4% and 90.1% improvement, respectively. Additionally, within a certain range, the photocatalytic performance increases with the reaction time and temperature.

Activated Carbon and Carbon Quantum Dots/Titanium Dioxide Composite Based on Waste Rice Noodles: Simultaneous Synthesis and Application in Water Pollution Control.

To achieve the full utilization of waste rice noodle (WRN) without secondary pollution, activated carbon (AC) and carbon quantum dots/titanium dioxide (CQDs/TiO2) composite were simultaneously synthesized by using WRN as raw material. Both of the two materials showed potential applications in water pollution control. The AC based on WRN displayed a porous spherical micro-morphology, which could absorb heavy metal elements like Pb(II) and Cr(VI) efficiently, with a maximum equilibrium uptake of 12.08 mg·g-1 for Pb(II) and 9.36 mg·g-1 for Cr(VI), respectively. The adsorption of the resulted AC could match the Freundlich adsorption isotherm and the pseudo-second-order kinetics mode. On the other hand, the CQDs/TiO2 composite based on WRN displayed a high efficient photocatalytic degradation effect on various water-soluble dyes such as methylene blue, malachite green, methyl violet, basic fuchsin, and rhodamine B under visible light irradiation, which showed better photocatalytic performance than commercial TiO2. The introduction of CQDs based on WRN to TiO2 could result in efficient electron-hole pair separation and enable more photogenerated electrons to reduce O2 and more photogenerated holes to oxidize H2O or OH-, which could cause stronger abilities in producing O2·- and ·OH radical and better photocatalytic activity.

Synthesis and properties of wax based on waste cooking oil.

In this work, a cost-effective wax was synthesized from waste cooking oil (WCO), and its properties including melting point, color, hardness, combustion performance and micro-morphology were tested and analyzed. The obtained results showed that the epoxy waste cooking oil had lighter color, higher melting point and hardness than that of original WCO, which could be used as wax. Moreover, introducing stearic acid further improved the performances of WCO-based wax. The WCO-based wax made of epoxy waste cooking oil and stearic acid (containing ≥50 wt% stearic acid) displayed a relatively high melting point (≥46 °C), light color (Lovibond color code Y ≤ 16.1, R ≤ 2.3), good hardness (needle penetration index ≤2.95 mm) and long combustion time (≥227 min), and could achieve the required national standard and be used as a substitute for the commercially available soybean wax. Together with many additional benefits such as low synthesis cost, mild reaction conditions, convenient synthesis route, and no secondary pollution, producing wax based on WCO could provide a new path for WCO recycling in economically trailing regions.

Fatty acid wax from epoxidation and hydrolysis treatments of waste cooking oil: synthesis and properties.

To provide low-cost wax and a new methodology for utilizing waste cooking oil (WCO), fatty acid wax based on WCO was synthesized by using epoxidation and hydrolysis treatments, whose properties included melting point, color, hardness, combustion properties, aldehyde content, and microscopic morphology were tested and analyzed. The obtained WCO-based wax contained mixed fatty acids, including palmitic acid and 9,10-dihydroxystearic acid as main constituents, which could form a 3D stable crossing network constructed by large long-rod crystals. The WCO-based wax with high fatty acid content (96.41 wt%) has a high melting point (44-53 °C), light color (Lovibond color code Y = 11.9, R = 2.3), good hardness (needle penetration index = 2.66 mm), long candle burning time (293 min), and low aldehyde content (7.98 × 10-2 µg g-1), which could be a lower-cost alternative of commercial soybean wax (SW) for producing various wax products including candles, crayons, waxworks, etc.

CQDs/ZnO composites based on waste rice noodles: preparation and photocatalytic capability.

To provide a low-cost photocatalyst and new methodology for the utilization of waste rice noodle (WRN), a carbon quantum dots/zinc oxide (CQDs/ZnO) composite using WRN as the raw material was synthesized and characterized. The CQDs/ZnO composite based on WRN exhibited a highly efficient photocatalytic degradation effect on various organic pollutants and could be a good alternative for commercial ZnO. For methylene blue, the CQDs/ZnO composite showed a good degradation rate of 99.58% within 40 min, a high degradation rate constant of 0.2630 min-1, and could be recycled and reused for ten photocatalytic cycles without an appreciable decrease in the degradation effect, which was much better than that of commercial ZnO. The resulting CQDs/ZnO composite also displayed a nice photocatalytic degradation effect on other common organic pollutants, such as malachite green, methyl violet, basic fuchsin, rhodamine B, aniline and tetracycline. In particular, it could achieve excellent photocatalytic degradation on malachite green with an extremely high degradation rate constant of 1.9260 min-1. Besides, the CQDs/ZnO composite could also be used to control the pollution of tetracycline or aniline. The introduction of CQDs based on WRN to ZnO resulted in efficient electron-hole pair separation and enabled more photogenerated electrons to reduce O2 and more photogenerated holes to oxidize H2O, which caused stronger abilities in producing radicals (such as O2˙- and ˙OH) and a better photocatalytic degradation effect to organic pollutants.

A Clinical Epidemiological Analysis of Prognostic Nutritional Index Associated with Diabetic Retinopathy.

PURPOSE: Prognostic nutritional index (PNI) is an effective tool to evaluate the nutritional conditions and predict prognosis, but clinical data are limited for the use of PNI in diabetic retinopathy (DR). This study aimed to investigate the relationship of PNI with the prevalence and severity of DR in patients with type 2 diabetes mellitus (T2DM). PATIENTS AND METHODS: This cross-sectional analysis enrolled 1023 individuals with T2DM hospitalized between 2017-2020. PNI was calculated as 10 × serum albumin (g/l) + 0.005 × total lymphocyte count (cells/mL). DR severity was categorized as no, nonproliferative, and vision-threatened DR (VTDR) according to the modified Airlie House classification. Multivariate-adjusted odds ratio (OR) with 95% confidence interval (CI) for the prevalent DR in the top (Q4) compared with the bottom quartile (Q1) of PNI levels were estimated by using logistic regression analyses. RESULTS: PNI levels were significantly lower in individuals with VTDR than those with no and nonproliferative DR (both P < 0.001), and the proportions of individuals with DR were significantly decreased in the top quartile compared with the bottom quartile of PNI levels (P < 0.001). After adjustments for age, gender, DM duration, obesity-related risk factors and clinical biochemical parameters, the higher levels of PNI were significantly associated with a lower prevalence of DR (Q4 vs Q1: OR = 0.402, 95% CI: 0.250-0.649, P < 0.001), with a 5.9% reduction in the prevalence of DR for a per-unit increment in the levels of PNI (OR = 0.941, 95% CI: 0.911-0.972, P < 0.001). The association of PNI and obesity-related indexes (body mass index and waist circumference) with the severity of DR was independent of each other (P<0.001). CONCLUSION: PNI was inversely and independently associated with the severity and prevalence of DR, which suggested that PNI could likely be used to predict DR prognosis in clinical practice.

Tertiary carbinamine synthesis by rhodium-catalyzed [3+2] annulation of N-unsubstituted aromatic ketimines and alkynes.

A convenient and waste-free synthesis of indene-based tertiary carbinamines by rhodium-catalyzed imine/alkyne [3+2] annulation is described. Under the optimized conditions of 0.5-2.5 mol % [{(cod)Rh(OH)}(2)] (cod=1,5-cyclooctadiene) catalyst, 1,3-bis(diphenylphosphanyl)propane (DPPP) ligand, in toluene at 120 degrees C, N-unsubstituted aromatic ketimines and internal alkynes were coupled in a 1:1 ratio to form tertiary 1H-inden-1-amines in good yields and with high selectivities over isoquinoline products. A plausible catalytic cycle involves sequential imine-directed aromatic C-H bond activation, alkyne insertion, and a rare example of intramolecular ketimine insertion into a Rh(I)-alkenyl linkage.

Cane Molasses Graphene Quantum Dots Passivated by PEG Functionalization for Detection of Metal Ions.

Poly(ethylene glycol) passivated graphene quantum dots (PEG-GQDs) were synthesized based on a green and effective strategy of the hydrothermal treatment of cane molasses. The prepared PEG-GQDs, with an average size of 2.5 nm, exhibit a brighter blue fluorescence and a higher quantum yield (QY) (up to approximately 21.32%) than the QY of GQDs without surface passivation (QY = 10.44%). The PEG-GQDs can be used to detect and quantify paramagnetic transition-metal ions including Fe3+, Cu2+, Co2+, Ni2+, Pb2+, and Mn2+. In the case of ethylenediaminetetraacetic acid (EDTA) solution as a masking agent, Fe3+ ions can be well selectively determined in a transition-metal ion mixture, following the lowest limit of detection (LOD) of 5.77 µM. The quenching mechanism of Fe3+ on PEG-GQDs belongs to dynamic quenching. Furthermore, Fe3+ in human serum can be successfully detected by the PEG-GQDs, indicating that the green prepared PEG-GQDs can be applied as a promising candidate for the selective detection of Fe3+ in clinics.

Duration of reproductive years and time since menopause were associated with metabolic syndrome in postmenopausal parous women of Chinese ancestry.

OBJECTIVE: Although duration of reproductive years and time since menopause were previously implicated in the metabolic syndrome, the evidence is more limited. Few of the previous studies were able to take into account related reproductive variables simultaneously. The aim of the present study was to explore the influence of these two reproductive factors on the prevalence of metabolic syndrome in postmenopausal parous women from Southeast China. METHODS: In all, 1,536 postmenopausal parous women were recruited. Self-reported information about reproductive status, including age at menarche, age at menopause, number of children, prepregnancy body weight, and oral contraceptive use, was collected, and duration of reproductive years and time since menopause were calculated. Clinical parameters related with metabolic syndrome were also measured. RESULTS: Longer duration of reproductive years was significantly related with increased presence of the metabolic syndrome (odds ratio [OR] 1.570, 95% confidence interval [CI] 1.091, 2.259 for tertile 2 group; OR 1.850, 95% CI 1.163, 2.944 for tertile 3 group; P for trend = 0.010). Women with more than 20 years since menopause were more likely to experience metabolic syndrome (OR 2.422, 95% CI 1.109, 5.286, P = 0.026) and elevated blood pressure (OR 3.239, 95% CI 1.406, 7.458, P = 0.006) when compared with those with less than 10 years since menopause. CONCLUSIONS: Longer duration of reproductive years and time since menopause were associated with higher prevalence of metabolic syndrome in postmenopausal parous women from Southeast China.

Solid alcohol based on waste cooking oil: Synthesis, properties, micromorphology and simultaneous synthesis of biodiesel.

Solid alcohols based on waste cooking oil (WCO) and other edible oils (butter or soybean oil) were synthesized by a simple one-step method. The effects of sodium hydroxide (NaOH) dosage and type of oil on the combustion performances were explored. IR spectroscopy and micro-morphologies of the oil based solid alcohols were also studied. Results showed that, for oil based solid alcohol, use of an appropriate excess of NaOH and an oil with lower iodine value produced the solid alcohol with better combustion performance. Centrifugation produced the bottom waste cooking oil (B-WCO) with lower iodine value and the supernatant waste cooking oil (S-WCO) with higher iodine value. The B-WCO afforded solid alcohol with longer combustion time, higher melting temperature and relatively low combustion residue rate, whereas the S-WCO could be used for synthesizing biodiesel.

Manganese(ii) enhanced fluorescent nitrogen-doped graphene quantum dots: a facile and efficient synthesis and their applications for bioimaging and detection of Hg2+ ions.

Manganese ion (Mn2+) bonded nitrogen-doped graphene quantum dots (Mn(ii)-NGQDs) with water solubility have been successfully synthesized by a simple, one-pot hydrothermal carbonization, using sodium citrate, glycine and manganese chloride as raw materials. The photoluminescence (PL) characteristics of Mn(ii)-NGQDs were studied in detail. The resulting Mn(ii)-NGQDs show a remarkably enhanced PL intensity and quantum yield (QY = 42.16%) compared with the product without Mn(ii)-doped (named as NG, QY = 27.06%) and the product doped with other metal ions. The Mn(ii)-NGQDs not only display low toxicity and high cellular uptake efficiency for fluorescence live cell imaging in biological evaluations but also exhibit a fast, highly selective and sensitive fluorescence quenching effect toward Hg2+ ions, with a detection limit of 3.4 × 10-8 mol L-1.

Efficacy and safety of ultrasound-guided percutaneous polidocanol sclerotherapy in benign predominantly cystic thyroid nodules: a prospective study.

OBJECTIVE: To evaluate the efficacy and safety of percutaneous polidocanol injection (PPI) in treatment of predominantly cystic thyroid nodules. MATERIALS AND METHODS: This prospective study included 111 patients with 122 benign predominantly cystic thyroid nodules inducing pressure symptoms or cosmetic problems. The nodules were randomized to a single aspiration with (n = 61) or without (n = 61) subsequent PPI and followed up after 1, 3, 6, and 12 months. Ten patients (12 nodules) declined to follow up after aspiration in group 2. Nodule volumes, symptoms scores, and cosmetic scores were evaluated before and after treatment. The therapeutic success rate and safety of PPI for treatment of predominantly cystic thyroid nodules were also evaluated. RESULTS: In the PPI group, the nodule volumes were reduced from 13.67 ± 9.90 to 2.60 ± 2.66 (p < .001). Therapeutic success rate (nodule volume reduction >50%) was obtained in 57 of 61 (93.44%) nodules in the PPI group, compared to seven of 49 (14.29%) in the aspiration group (p < .001). In the aspiration group, the nodule volume was not significantly reduced. The reduction in symptom scores was significantly higher in the PPI group (from 3.60 ± 1.65 to 1.60 ± 1.19) than in the aspiration group (from 3.62 ± 1.89 to 3.30 ± 1.06) (p < .001, between groups). The reduction in cosmetic scores showed a significant difference between groups (p < .001). In total, 4.92% of patients (3/61) in the PPI group and 85.71% (42/49) in the aspiration group showed recurrence during the follow-up period. There was a significant difference in the recurrence rate between groups (p < .001). No major side-effects occurred. CONCLUSIONS: US-guided PPI of benign recurrent predominantly cystic thyroid nodules is effective and safe. PPI is an important alternative to benign recurrent predominantly cystic thyroid nodules.

G6PD deficiency-induced hemolysis in a Chinese diabetic patient: a case report with clinical and molecular analysis.

A 59-year-old Chinese male patient was admitted at diagnosis of type 1 diabetes with ketoacidosis. During the normalization of blood glucose with insulin, the patient developed acute hemolysis. The factors predisposing to hemolysis were not found, except the significantly diminished activity of glucose-6-phosphate dehydrogenase (G6PD). DNA analysis did not show any coding or intronic mutation in the G6PD gene. This is the first reported case of a Chinese patient in diabetic ketoacidosis with hemolysis induced by G6PD deficiency in the absence of mutations in the G6PD gene.

(AEDPH3)·(BtaH): a novel supramolecular plaster with formaldehyde adsorption and formaldehyde/ultraviolet ray-induced luminescence switching performance.

A novel supramolecular plaster, (AEDPH(3))·(BtaH) (1), is synthesised and characterized. The supramolecular plaster is easy to synthesise and process, and displays good mechanical properties. It can adsorb and eliminate formaldehyde (HCHO) with high efficiency and exhibits very interesting HCHO/ultraviolet ray-induced luminescence switching.

Zn(II)-PEG 300 globules as soft template for the synthesis of hexagonal ZnO micronuts by the hydrothermal reaction method.

Hexagonal ZnO micronuts (HZMNs) have been successfully synthesized with the assistance of poly(ethylene glycol) (PEG) 300 via a hydrothermal method. The structure and morphology of the HZMNs were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and selected area electron diffraction (SAED). An individual ZnO micronut is revealed as twinned crystals. Time-dependent investigation shows that the growth of HZMNs involves a dissolution-recrystallization process followed by Ostwald ripening, in which is the first formed solid ZnO particles dissolve and transform to HZMNs with hollow structure. PEG 300 has been found to play a crucial role in the growth of this unique hollow structure. TEM observations show that the PEG chains aggregate to globules in water, which then have interaction with the dissolved zinc species to form the globules in a coiled state under hydrothermal conditions. These Zn(II)-PEG 300 globules act as soft template for the growth of HZMNs, and the possible growth mechanism is proposed. The room-temperature photoluminescence (PL) spectrum shows red emission around 612 nm with a full width at half-maximum (fwhm) only about 13 nm.

[The effect of angiotensin-(1-7) on the mRNA expression of PDGF and TGF-beta1 in the kidney of diabetic rats].

AIM: To study the effect of angiotensin-(1-7) on the kidney of diabetic rats by observing the mRNA expression of PDGF and TGF-beta1. METHODS: SD rats were divided into three groups: Group C (uni-nephrectomy control group), Group D (diabetic model control group), Group T (Ang-(1-7) treated group). We evaluated blood glucose,urea nitrogen, creatinine and urine albumin excretion respectively, studied the renal morphology by light microscope, and detected the gene expression of PDGF, TGF-beta1 in renal tissue by RT-PCR technique. RESULTS: There was significant difference between the group D and T about the RW/BW, renal morphology, the total urine protein and the mRNA expression of PDGF and TGF-beta1. CONCLUSION: Ang-(1-7) can relieve the renal process of diabetic rats.