How does calcium and sodium in saline water affect the potential of different rates and size of sugarcane biochar to soil water repellency remediation?

Soil water repellency (SWR) is a growing problem in arid and semiarid regions with non-saline water limitations. The objective of this study was to investigate the potential of different rates and sizes of sugarcane biochar on reducing soil water hydrophobicity when using saline and non-saline water. Eleven sugarcane biochar application rates from 0 to 10% with two different sizes including <0.25 and 0.25-1 mm were studied. The experiment was conducted in two strongly and extremely water-repellent soil. In addition, to investigate the effect of electrolyte concentration on biochar potential for SWR reduction, calcium chloride and sodium chloride electrolyte solutions with 5 concentrations including 0, 0.15, 0.3, 0.45 and 0.6 mol L-1 were considered. The results showed that both sizes of biochar reduced the soil water repellency. While in strongly repellent soil the 4% biochar was enough to change the soil from strongly repellent to hydrophilic, in extremely water-repellent soil, the use of 8% of fine biochar and 6% of coarse biochar changed the extremely water-repellent soil to slightly hydrophobic and strongly hydrophobic respectively. Increasing the electrolyte concentration caused the expansion of soil hydrophobicity and reduced the positive effect of biochar to water repellency management. Increasing the electrolyte concentration in sodium chloride solution has a greater effect on increasing hydrophobicity than in calcium chloride solution. In conclusion, biochar could suggest as a soil-wetting agent in these two hydrophobic soils. However, the salinity of water and the its dominant ion could increase the amount of biochar for soil repellency reduction.

Remediation of an oil-contaminated soil by two native plants treated with biochar and mycorrhizae.

Soil contamination by petroleum compounds threatens the health of soil and water resources. This research was conducted with the objective of reaching an efficient technique for the removal or reduction of harmful effects caused by total petroleum hydrocarbons (TPH) in soils. In a greenhouse experiment, the effect of biochar (B), mycorrhizae (M) and combination of mycorrhizae and biochar (M + B) on the growth of two native species; clover (Trifolium arvense) and mallow (Malva sylvestris L.), and removal efficiency of TPH (16.79 mg kg-1) from an oil-contaminated soil were studied. The plant analyses after 50 days of growth period showed a significant (p ≤ 0.05) increase in shoot dry weight of mallow in B and M + B treatments but no significant effect was observed for clover compared to the control (C). The initial TPH concentration, determined by gas chromatography technique was reduced from 9.4% in unplanted soil until 56.4% (clover) and 55.9% (mallow) in M + B treatment. The relative concentration of long chain alkanes (LCAs) were also reduced when treatments were applied, in which the highest and lowest reductions was found in C21-C25 and C11-C15, respectively, though octacosane (C28) was increased or unchanged in soil. This result suggests that likely the occurrence of C28 in the mycorrhizal hyphae or the higher removal of the other alkanes increase octacosane relative concentration in soil, which more research is necessary.

Phytoremediation of a petroleum-polluted soil by native plant species in Lorestan Province, Iran.

Petroleum hydrocarbons are potentially toxic for organisms due to the inherent properties, such as solubility, volatility, and biodegradability. The petroleum materials released from corroded old pipelines would pollute soils, shallow groundwater and air as a consequence, and threat the health of human and environment. Therefore, the removal of these compounds from environment is vital. The stability of these pollutants at the soil and their gradual accumulation over time would disrupt the normal function of the soil, such as reduced agricultural capability. In this research, the influence of two plant species (Bromus tectorum L. and Festuca arundinacea) with different amendments including arbuscular mycorrhizal fungi, alfalfa residues, and nutrient solution on the degradation rate of petroleum hydrocarbons in soil was studied. The results showed that the most effective treatment for petroleum remediation was related to B. tectorum L. plant when treated with mycorrhizal fungi and nutrient solution. The degradation rate during 40 days was about 83.27% when compared to the control. Arbuscular mycorrhizal associations are important in the restoration of degraded ecosystems because of the benefits to their symbiotic partners. This fungal phytotechnological mechanism is still in its infancy and there has been little research on aged-contaminated soils.