Torrefaction interpretation through morphological and chemical transformations of agro-waste to porous carbon-based biofuel.

In the current study, two agro-waste lignocellulosic corncob (CC) and rice husk (RH) were thermally torrefied at 200-300 °C into a porous carbon-enriched biofuel. The scanning electron microscopy (SEM) of produced biofuel confirmed the rounded, homogenous, and spherical structure of the produced biofuels with higher porosity at a temperature between 250 and 300 °C with 60 min retention time. Brunauer-Emmett-Teller (BET) analysis indicated the high surface area (CC: 1.19-2.87 m2 g-1 and RH: 1.22-2.67 m2 g-1) and pore volume (CC: 1.23-2.81 ×10-3 m3 g-1 and RH: 1.46-2.58 ×10-3 m3 g-1). Crystallinity index decline percent (CC= 62.87% and RH=57.10%) estimated thermal stability and rise in amorphous cellulose reformation during (250-300 °C)/60 min that would efficiently hydrolyze during oxidative pyrolysis carbon reactive sites the rise in surface area and total pore's volume, having higher conversion rate as compared to raw materials. Carbon content was upgraded to 94% by eliminating hydrogen and oxygen from lignocellulosic agro-waste to produce energy-dense CC and RH. The lignin macromolecule transformation extent was estimated by O/C trend, which was equal to 63% and 47% for CC and RH, respectively, at 300 °C for 60 min. Due to low bulk density and pre-grinding energy requirements, torrefied biofuel with decomposed fibrous structure have lower transportation costs.

Fe-zeolite catalyst for ozonation of pulp and paper wastewater for sustainable water resources.

The pulp and paper industry consumes enormous quality of freshwater, leading to wastewater. It must be treated to remove pollutants, particularly residual dyestuffs, before releasing them to water bodies to avoid adverse environmental effects. The traditional wastewater treatment methods used for the pulp and paper industry are less efficient in colour and chemical oxygen demand (COD) removal. The current study is aimed at developing a novel catalyst for the catalytic ozonation of pulp and paper wastewater with better colour and COD removal for sustainable resources of clean water. The proposed catalyst is impregnated by iron on natural zeolites. Various parameters such as catalyst dose, pH, ozone dose, initial COD concentration, and reaction time are studied and optimized. The performance was evaluated by comparing the results with the single ozonation process (SOP) and catalytic ozonation process (COP). The highest COD and colour reduction efficiencies have been achieved, i.e., 71%, and 88% at a natural pH of 6.8. The proposed process achieved higher COD and colour efficiencies than the single ozonation process and catalytic ozonation process using raw zeolites. The improvement in efficiencies are 23% and 29% for SOP and 17% and 19% for COP, respectively. Hence, the results proposed the sustainability and applicability of COP to treat paper and pulp sector effluent.