Targeted Writing and Deleting of Magnetic Skyrmions in Two-Terminal Nanowire Devices.

Controllable writing and deleting of nanoscale magnetic skyrmions are key requirements for their use as information carriers for next-generation memory and computing technologies. While several schemes have been proposed, they require complex fabrication techniques or precisely tailored electrical inputs, which limits their long-term scalability. Here, we demonstrate an alternative approach for writing and deleting skyrmions using conventional electrical pulses within a simple, two-terminal wire geometry. X-ray microscopy experiments and micromagnetic simulations establish the observed skyrmion creation and annihilation as arising from Joule heating and Oersted field effects of the current pulses, respectively. The unique characteristics of these writing and deleting schemes, such as spatial and temporal selectivity, together with the simplicity of the two-terminal device architecture, provide a flexible and scalable route to the viable applications of skyrmions.

Magnetism in dopant-free ZnO nanoplates.

It is known that bulk ZnO is a nonmagnetic material. However, the electronic band structure of ZnO is severely distorted when the ZnO is in the shape of a very thin plate with its dimension along the c-axis reduced to a few nanometers while keeping the bulk scale sizes in the other two dimensions. We found that the chemically synthesized ZnO nanoplates exhibit magnetism even at room temperature. First-principles calculations show a growing asymmetry in the spin distribution within the distorted bands formed from Zn (3d) and O (2p) orbitals with the reduction of thickness of the ZnO nanoplates, which is suggested to be responsible for the observed magnetism. In contrast, reducing the dimension along the a- or b-axes of a ZnO crystal does not yield any magnetism for ZnO nanowires that grow along c-axis, suggesting that the internal electric field produced by the large {0001} polar surfaces of the nanoplates may be responsible for the distorted electronic band structures of thin ZnO nanoplates.

Electrical Generation and Deletion of Magnetic Skyrmion-Bubbles via Vertical Current Injection.

The magnetic skyrmion is a topologically protected spin texture that has attracted much attention as a promising information carrier because of its distinct features of suitability for high-density storage, low power consumption, and stability. One of the skyrmion devices proposed so far is the skyrmion racetrack memory, which is the skyrmion version of the domain-wall racetrack memory. For application in devices, skyrmion racetrack memory requires electrical generation, deletion, and displacement of isolated skyrmions. Despite the progress in experimental demonstrations of skyrmion generation, deletion, and displacement, these three operations have yet to be realized in one device. Here, a route for generating and deleting isolated skyrmion-bubbles through vertical current injection with an explanation of its microscopic origin is presented. By combining the proposed skyrmion-bubble generation/deletion method with the spin-orbit-torque-driven skyrmion shift, a proof-of-concept experimental demonstration of the skyrmion racetrack memory operation in a three-terminal device structure is provided.

Programmable Dynamics of Exchange-Biased Domain Wall via Spin-Current-Induced Antiferromagnet Switching.

Magnetic domain wall (DW) motion in perpendicularly magnetized materials is drawing increased attention due to the prospect of new type of information storage devices, such as racetrack memory. To augment the functionalities of DW motion-based devices, it is essential to improve controllability over the DW motion. Other than electric current, which is known to induce unidirectional shifting of a train of DWs, an application of in-plane magnetic field also enables the control of DW dynamics by rotating the DW magnetization and consequently modulating the inherited chiral DW structure. Applying an external bias field, however, is not a viable approach for the miniaturization of the devices as the external field acts globally. Here, the programmable exchange-coupled DW motion in the antiferromagnet (AFM)/ferromagnet (FM) system is demonstrated, where the role of an external in-plane field is replaced by the exchange bias field from AFM layer, enabling the external field-free modulations of DW motions. Interestingly, the direction of the exchange bias field can also be reconfigured by simply injecting spin currents through the device, enabling electrical and programmable operations of the device. Furthermore, the result inspires a prototype DW motion-based device based on the AFM/FM heterostructure, that could be easily integrated in logic devices.

Enhancing the conductivity of PEDOT:PSS films for biomedical applications via hydrothermal treatment.

This paper reports a new biocompatible conductivity enhancement of poly (3,4-ethylenedioxythiophene):poly (styrene sulfonate) (PEDOT:PSS) films for biomedical applications. Conductivity of PEDOT:PSS layer was reproducibly from 0.495 to 125.367 S cm-1 by hydrothermal (HT) treatment. The HT treatment employs water (relative humidity > 80%) and heat (temperature > 61 °C) instead of organic solvent doping and post-treatments, which can leave undesirable residue. The treatment can be performed using the sterilizing conditions of an autoclave. Additionally, it is possible to simultaneously reduce the electrical resistance, and sterilize the electrode for practical use. The key to conductivity enhancement was the structural rearrangement of PEDOT:PSS, which was determined using atomic force microscopy, X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and ultraviolet-visible spectroscopy. It was found that PEDOT inter-bridging occurred as a result of the structural rearrangement. Therefore, the conductivity increased on account of the continuous conductive pathways of the PEDOT chains. To test the biocompatible enhancement technique for biomedical applications, certain demonstrations, such as the monitoring of joint movements and skin temperature, and measuring electrocardiogram signals were conducted with the hydrothermal-treated PEDOT:PSS electrode. This simple, biocompatible treatment exhibited significant potential for use in other biomedical applications as well.

Direct Demonstration of Topological Stability of Magnetic Skyrmions via Topology Manipulation.

Topological protection precludes a continuous deformation between topologically inequivalent configurations in a continuum. Motivated by this concept, magnetic skyrmions, topologically nontrivial spin textures, are expected to exhibit topological stability, thereby offering a prospect as a nanometer-scale nonvolatile information carrier. In real materials, however, atomic spins are configured as not continuous but discrete distributions, which raises a fundamental question if the topological stability is indeed preserved for real magnetic skyrmions. Answering this question necessitates a direct comparison between topologically nontrivial and trivial spin textures, but the direct comparison in one sample under the same magnetic fields has been challenging. Here we report how to selectively achieve either a skyrmion state or a topologically trivial bubble state in a single specimen and thereby experimentally show how robust the skyrmion structure is in comparison with the bubbles. We demonstrate that topologically nontrivial magnetic skyrmions show longer lifetimes than trivial bubble structures, evidencing the topological stability in a real discrete system. Our work corroborates the physical importance of the topology in the magnetic materials, which has hitherto been suggested by mathematical arguments, providing an important step toward ever-dense and more-stable magnetic devices.

Universal field-tunable terahertz emission by ultrafast photoinduced demagnetization in Fe, Ni, and Co ferromagnetic films.

We report a universal terahertz (THz) emission behavior from simple Ni, Fe, and Co metallic ferromagnetic films, triggered by the femtosecond laser pulse and subsequent photoinduced demagnetization on an ultrafast time scale. THz emission behavior in ferromagnetic films is found to be consistent with initial magnetization states controlled by external fields, where the hysteresis of the maximal THz emission signal is observed to be well-matched with the magnetic hysteresis curve. It is experimentally demonstrated that the ultrafast THz emission by the photoinduced demagnetization is controllable in a simple way by external fields as well as pump fluences.

Role of non-thermal electrons in ultrafast spin dynamics of ferromagnetic multilayer.

Understanding of ultrafast spin dynamics is crucial for future spintronic applications. In particular, the role of non-thermal electrons needs further investigation in order to gain a fundamental understanding of photoinduced demagnetization and remagnetization on a femtosecond time scale. We experimentally demonstrate that non-thermal electrons existing in the very early phase of the photoinduced demagnetization process play a key role in governing the overall ultrafast spin dynamics behavior. We simultaneously measured the time-resolved reflectivity (TR-R) and the magneto-optical Kerr effect (TR-MOKE) for a Co/Pt multilayer film. By using an extended three-temperature model (E3TM), the quantitative analysis, including non-thermal electron energy transfer into the subsystem (thermal electron, lattice, and spin), reveals that energy flow from non-thermal electrons plays a decisive role in determining the type I and II photoinduced spin dynamics behavior. Our finding proposes a new mechanism for understanding ultrafast remagnetization dynamics.

Room-temperature, texture-controlled growth of ZnO thin films and their application for growing aligned ZnO nanowire arrays.

Texture-controlled growth of ZnO films on substrates of general materials at room temperature by pulsed laser deposition was demonstrated. The texture of the film changed progressively from (001) to (110) to (100) as the laser fluence increased from 2 J cm(-2) up to 45 J cm(-2). Application of the textured films on Si wafers as seed layers for growing aligned ZnO nanowire arrays (grown along the c-axis) with controlled orientation relative to the substrate surface was demonstrated. The individual nanowire forms an epitaxial orientation relationship with the orientation of the grain that nucleated it; therefore the long axis of the nanowire aligns in conformity with the texture of the seed layer.

Accurate, hysteresis-free temperature sensor for health monitoring using a magnetic sensor and pristine polymer.

Herein, a novel temperature sensor is proposed employing a planar Hall resistance (PHR) magnetic sensor, a magnet sheet, and an expanding polymer. It features a tunable temperature range, high linear sensitivity, accuracy, and cycling stability through 1000 cycles, and no thermal hysteresis. This new sensor is promising as a body temperature sensor.

Dynamics of the Bloch point in an asymmetric permalloy disk.

A Bloch point (BP) is a topological defect in a ferromagnet at which the local magnetization vanishes. With the difficulty of generating a stable BP in magnetic nanostructures, the intrinsic nature of a BP and its dynamic behaviour has not been verified experimentally. We report a realization of steady-state BPs embedded in deformed magnetic vortex cores in asymmetrically shaped Ni80Fe20 nanodisks. Time-resolved nanoscale magnetic X-ray imaging combined with micromagnetic simulation shows detailed dynamic character of BPs, revealing rigid and limited lateral movements under magnetic field pulses as well as its crucial role in vortex-core dynamics. Direct visualizations of magnetic structures disclose the unique dynamical feature of a BP as an atomic scale discrete spin texture and allude its influence on the neighbouring spin structures such as magnetic vortices.

Ultrahigh photosensitivity of the polar surfaces of single crystalline ZnO nanoplates.

Single crystalline ZnO nanoplatelet structures were synthesized via a hydrothermal process on the surface of GaN microparticles. Growth of ZnO seeded on the GaN surface promoted faster growth along the directions within the basal plane of the ZnO crystal structure, resulting in the formation of 2-dimensional nanoplates with a thickness less than a few tens of nanometers at most. Electrical conduction across an individual nanoplate was measured and found to be extremely sensitive to UV illumination and the surrounding atmospheric environment. Such electrical behaviors of the nanoplates were attributed to the dominance of the polar (0001) surfaces and the adsorption and desorption of the ambient gas molecules on these surfaces. Their coupling with conduction electrons near the surface is the critical factor responsible for the highly sensitive electrical properties of the nanoplate. Virtually the entire volume of the nanoplates is under the influence of the surface adsorbed molecules, which changes the electrical properties of the nanoplates extensively, depending on their environmental conditions. Combining the very high photocurrent to dark current ratio and the high effective resistance of the ZnO nanoplates reported in the present study, ultrasensitive photo-devices operating at very low power can be expected with the use of 2-dimensional nanoplates.

Bidirectional propagation of tilting domain walls in perpendicularly magnetized T shaped structure with the interfacial Dzyaloshinskii-Moriya interaction.

Understanding of domain wall (DW) propagation in a complex structure is an essential first step toward the development of any magnetic-domain based devices including spin-based logic or magnetic memristors. Interfacial Dzyaloshinskii-Moriya interaction (iDMI) in the structure with broken inversion symmetry induces an asymmetrical DW configuration with respect to the direction of in-plane field. Dynamic behaviors of field-driven DW within the film with perpendicular magnetic anisotropy is influenced by DW tilt from the iDMI effect and the corners in the T-shaped structure of the DW path. Images from Kerr microscopy reveal that the iDMI effective field contributes to a tilted structure of DW configuration and evolution along its propagation. With the combination of iDMI and T-shaped structure, we observed two distinguished bidirectional DW propagations in two output branches and distinct arriving times at the destination pads with a uniform external field. Micromagnetic simulation results is compared with the observed dynamics of a DW configuration in the structure providing an additional confirmation of the interpreted results.

Magnetism of the hypo-oxide state at the diffuse interface between the ferromagnet and antiferromagnet phases.

At the interface between ferromagnetic and antiferromagnetic phases, various spin configurations with a higher degrees of complexity than in the bulk states can be derived due to the diverse possible interface atomic structures, where coupling interactions among the constituting atoms can form in consistence with altered atomic configurations. The interface magnetic properties then depend on the collective behavior of such spin structures. In the present work, an extended interfacial configuration of a hypo-oxide state was prepared by establishing the gradient of oxygen concentration across the spatially diffuse interface region between ferromagnetic metallic and antiferromagnetic oxide phases at the nanometer scale. With these mixed ferromagnetic and antiferromagnetic couplings among the atoms in the interfacial hypo- or sub-oxide state, novel magnetic behavior can be induced. We report here, for the first time, a significant increase of saturation magnetization with temperature over a broad temperature range, which is against the conventional expectation for any generally known magnetic materials. And the unusual temperature dependent behavior can be understood as the combined effects of competing ferromagnetic and antiferromagnetic couplings acting on atoms in and near the interface region.

Spin-orbit torque-driven skyrmion dynamics revealed by time-resolved X-ray microscopy.

Magnetic skyrmions are topologically protected spin textures with attractive properties suitable for high-density and low-power spintronic device applications. Much effort has been dedicated to understanding the dynamical behaviours of the magnetic skyrmions. However, experimental observation of the ultrafast dynamics of this chiral magnetic texture in real space, which is the hallmark of its quasiparticle nature, has so far remained elusive. Here, we report nanosecond-dynamics of a 100nm-diameter magnetic skyrmion during a current pulse application, using a time-resolved pump-probe soft X-ray imaging technique. We demonstrate that distinct dynamic excitation states of magnetic skyrmions, triggered by current-induced spin-orbit torques, can be reliably tuned by changing the magnitude of spin-orbit torques. Our findings show that the dynamics of magnetic skyrmions can be controlled by the spin-orbit torque on the nanosecond time scale, which points to exciting opportunities for ultrafast and novel skyrmionic applications in the future.

Stochastic formation of magnetic vortex structures in asymmetric disks triggered by chaotic dynamics.

The non-trivial spin configuration in a magnetic vortex is a prototype for fundamental studies of nanoscale spin behaviour with potential applications in magnetic information technologies. Arrays of magnetic vortices interfacing with perpendicular thin films have recently been proposed as enabler for skyrmionic structures at room temperature, which has opened exciting perspectives on practical applications of skyrmions. An important milestone for achieving not only such skyrmion materials but also general applications of magnetic vortices is a reliable control of vortex structures. However, controlling magnetic processes is hampered by stochastic behaviour, which is associated with thermal fluctuations in general. Here we show that the dynamics in the initial stages of vortex formation on an ultrafast timescale plays a dominating role for the stochastic behaviour observed at steady state. Our results show that the intrinsic stochastic nature of vortex creation can be controlled by adjusting the interdisk distance in asymmetric disk arrays.

Ultrasound-induced ordering in poly(3-hexylthiophene): role of molecular and process parameters on morphology and charge transport.

Facile methods for controlling the microstructure of polymeric semiconductors are critical to the success of large area flexible electronics. Here we explore ultrasonic irradiation of solutions of poly(3-hexylthiophene) (P3HT) as a simple route to creating ordered molecular aggregates that result in a one to two order of magnitude improvement in field effect mobility. A detailed investigation of the ultrasound induced phenomenon, including the role of solvent, polymer regioregularity (RR) and film deposition method, is conducted. Absorption spectroscopy reveals that the development of low energy vibronic features is dependent on both the regioregularity as well as the solvent, with the latter especially influential on the intensity and shape of the band. Use of either higher regioregular polymer or ultrasonic irradiation of lower regioregular polymer solutions results in high field effect mobilities that are nearly independent of the dynamics of the film formation process. Surprisingly, no distinct correlation between thin-film morphology and macroscopic charge transport could be ascertained. The relationships between molecular and process parameters are very subtle: modulation of one effects changes in the others, which in turn impact charge transport on the macroscale. Our results provide insight into the degree of control that is required for the development of reproducible, robust materials and processes for advanced flexible electronics based on polymeric materials.

Characterization of impurity doping and stress in Si/Ge and Ge/Si core-shell nanowires.

Core-shell nanowires (NWs) composed of silicon (Si) and germanium (Ge) are key structures for realizing high mobility transistor channels, since the site-selective doping and band-offset in core-shell NWs separate the carrier transport region from the impurity doped region, resulting in the suppression of impurity scattering. Four different types of Si/Ge (i-Si/n-Ge, p-Si/i-Ge) and Ge/Si (n-Ge/i-Si, i-Ge/p-Si) core-shell NWs structures were rationally grown. The surface morphology significantly depended on the types of the core-shell NWs. Raman and X-ray diffraction (XRD) measurements clearly characterized the compressive and tensile stress in the core and shell regions. The observation of boron (B) and phosphorus (P) local vibrational peaks and the Fano effect clearly demonstrated that the B and P atoms are selectively doped into the shell and core regions and electrically activated in the substitutional sites, showing the success of site-selective doping.

Toward robust nanogenerators using aluminum substrate.

Nanogenerators (NG) have been developed to harvest mechanical energy from environmental sources such as vibration, human motion, or movement of automobiles. We demonstrate a robust and large-area NG based on a cost-effective Al substrate with the capability to be easily integrated in series and parallel for high-output performance. The output voltage and current density of the three-dimensionally integrated NG device reaches up to 3 V and 195 nA under human walking conditions.