Spectroscopic and Photo-Physical Properties of Near-IR Laser Dye in Novel Benign Green Solvents.

IR-792 as near IR (NIR) laser dye was dissolved with different concentrations in two types of ionic liquids (ILs) of different anion and cation, 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide (EMIM TFSI) & 1-Butyl-3-methylimidazolium tetrafluoroborate (BMIM BF4), as the benign green solvent and in methanol (MeOH) as a standard solvent. The behavior of fluorescence of IR-792 dye was studied. The fluorescence of IR-792 dissolved in the ILs was heavily compared to organic solvent. Some photo-physical parameters of IR-792 were calculated. Mainly, IR-792 had a very low quantum yield of fluorescence with high intersystem crossing rate & fluorescence lifetime in picosecond range. Optical absorption and behavior of fluorescence for the rigorously the purified imidazolium ILs in the neat condition and effect of IR-792 on their fluorescence have been examined. The emission behavior of IR-792 in green solvents was independent upon the wavelength of excitation, while the emission behavior of green solvents dependent upon the wavelength of excitation whether in pure state or with NIR laser dye. At most, the intensity of fluorescence of ILs is dependent upon dye concentration.

Spectroscopic Study of Solvent Polarity on the Optical and Photo-Physical Properties of Novel 9,10-bis(coumarinyl)anthracene.

Novel 7,7'-((anthracene-9,10-diylbis(methylene))bis(oxy))bis(4-methyl-2H-chromen-2-one) (BisCA) was prepared as fluorescent probe. The chemical structure of the novel BisCA was confirmed by spectroscopic data as well as elemental analyses. The solvatochromic characteristics of the new proble and its precursors were investigated in different solvents including, ethanol, DMF and toluene as protic polar, aprotic polar and non-polar solvents, respectively. Photo-physical parameters of probes, such as fluorescence quantum yields, fluorescence lifetime of excited state, radiative and non-radiative decay, were assessed in different media. The intermolecular H-bond effect on absorption and excitation spectra of the novel probe was reported in different solvents. Also, Onsager cavity radius and dipole moment of ground state and excited state of the probe were calculated as described by Bakhshiev and Reichardt methods.

Optical, photo physical parameters and photo stability of 6-Substituted-1, 2, 4-Triazine mono glucosyl derivative to act as a laser dye in various solvents.

The optical properties of a visible absorption range6-Substituted-1, 2, 4-Triazine mono glucosyl fluorescent derivative dye, such as absorption spectra, emission spectra in different solvents, were experimentally investigated. As well, some important photo physical parameters such as extinction coefficient (ε), cross-sections of the absorption (σa) and the emission (σe), quantum yield (фf), fluorescence lifetime, oscillator strength (f), the dipole moment (µ), decay rate radiative constant (kr), energy yield of fluorescence (Ef) and the length of attenuation Λ (λ) were assessed. The ground-state (µg) and excited-state (µe) dipole moments by solvatochromic correlations method were reported. The dye amplified spontaneous emission (ASE) of 2 × 10-4M with different input pumping energies of a continuous wave blue diode laser (λ = 450 nm) was studied. Photostability of dye was observed that was decreased to 53% of its initial energy by pumping with 100 mW of diode laser after exposure to 120 min.